copper(II) isonicotinate nicotinate | 1027001-55-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: copper(II) isonicotinate nicotinate
• 英文别名: [Cu(nicotinate)(isonicotinate)]n；[Cu(nic)(isonic)]n；[Cu(4-pyridinecarboxylate)(nicotinate)]；[Cu(ina)(na)]
• CAS: 1027001-55-3
• 化学式: C₆H₄NO₂*C₆H₄NO₂*Cu
• 分子量: 307.753
• InChiKey: MJFZISOZRHDIPC-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  烟酸 、 异烟酸 、 copper(II) perchlorate 以 水 为溶剂， 以71%的产率得到copper(II) isonicotinate nicotinate
  参考文献：
  名称：

  Synthesis, crystal structure and luminescence of novel two-dimensional interpenetrating frameworks

  摘要：

  Two novel metal coordination polymers, [Zn(nic)(isonic)](n) (1) and [Cu(nic)(isonic)](n) (2) (H(2)nic = nicotinic acid, H(2)isonic = isonicotinic acid), have been hydrothermally synthesized and characterized by elemental analysis, IR, and single crystal X-ray diffraction. X-ray single-crystal structural analyses reveal that 1 and 2 are isomorphous, two-dimensional interpenetrating (4, 4) frameworks bridged by nic and isonic ligands, and further assembled into a three-dimensional supramolecular structure via pi-pi stacking interaction. Moreover, 1 displayed photoluminescent properties in the blue range at room temperature. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.03.019

文献信息

• Syntheses, Structures and Characterisation of Two Cu ^II Polymers with 8‐Connected Topologies Based on Highly Connected SBUs
  作者：Jian Zhang、Yao Kang、Jie Zhang、Zhao‐Ji Li、Ye‐Yan Qin、Yuan‐Gen Yao

  DOI：10.1002/ejic.200500904

  日期：2006.6

  Two hydrothermally synthesised 3D metal-coordination polymers, namely [Cu(isonicotinate)(nicotinate)]n (1), with an 8-connected CsCl topology, and [Cu2(μ3-OH)(isonicotinate)2(BDC)0.5]n (2), with an unusual 8-connected 35.411.58.64 topology, demonstrate that highly connected SBUs can be employed in the construction of complicated frameworks. The temperature-dependent magnetic susceptibilities for the

  两种水热合成的 3D 金属配位聚合物，即 [Cu(异烟酸盐)(烟酸盐)]n (1)，具有 8 个连接的 CsCl 拓扑结构，以及 [Cu2(μ3-OH)(异烟酸盐)2(BDC)0.5]n (2) 具有不寻常的 8 连接 35.411.58.64 拓扑，证明高度连接的 SBU 可用于构建复杂框架。还测定了两种配合物的温度依赖性磁化率。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
• Copper coordination polymers containing pyridinecarboxylate and multicarboxylate: [Cu1.5(ina)(btcH)]·H2O, [Cu2(ina)2(bdc)0.5(μ3-OH)], and [Cu(ina)(na)] (inaH=4-pyridinecarboxylic acid, btcH3=1,3,5-benzenetricarboxylic acid, bdcH2=1,3-benzenedicarboxylic acid, naH=3-pyridinecarboxylic acid)
  作者：Hyun Sue Huh、Soon W. Lee

  DOI：10.1016/j.molstruc.2006.06.005

  日期：2007.3

  Under hydrothermal conditions, three copper coordination polymers, [Cu-1,Cu-5(ina)(btcH)](H2O)-H-. (1), [Cu-2(ina)(2)(bdc)(0.5)(mu(3)-OH)] (2), and [Cu(ina)(na)] (3), were prepared from Cu(NO3)(2)(.)2.5H(2)O and a combination of pyridinecarboxylic acid 14-pyridinecarboxylic (isonicotinic acid, inaH) or 3-pyridinecarboxylic (nicotinic acid, naH)} and multicarboxylic acid 1,3-benzenedicarboxylic acid (1,3-bdCH(2)) or 1,3,5-benzenetricarboxylic acid (1,3,5-btcH(3))}. These polymers were structurally characterized by X-ray diffraction. All polymers have a 2-D layer structure, which consists of rectangles of 7.9 x 8.9 (1), 9.0 x 8.2 (2), or 10.9 x 12.9 angstrom (3). (c) 2006 Elsevier B.V. All rights reserved.