5,6-disiladecane | 123148-49-2

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: 5,6-disiladecane
• 英文别名: Butyl(butylsilyl)silane
• CAS: 123148-49-2
• 化学式: C₈H₂₂Si₂
• 分子量: 174.434
• InChiKey: MPBPCZGGMVYUGN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.68
• 重原子数：
  10
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  正丁基锂 、 1,2-bis(trifluoromethanesulfonyloxy)disilane 以 正己烷 、 甲苯 为溶剂， 以71%的产率得到5,6-disiladecane
  参考文献：
  名称：

  Long-chain alkanes with an internal H2SiSiH2 linkage

  摘要：

  1,2-Bis(p-tolyl)disilane (2) has been prepared through Wurtz-coupling of chloro(p-tolyl)silane using lithium metal. It was used as a precursor for 1,2-bis(trifluoromethanesulfonyloxy)disilane (1), which was obtained by treatment with two equivalents of trifluoromethanesulfonic acid. This intermediate was treated with n-BuLi, n-HexLi or n-OctMgBr to give the title compounds (n-CnH2n+1)SiH2SiH2(n-CnH2n+1) (n = 4,6,8), 4a-c. Treatment of 2 with only one equivalent of triflic acid gave p-TolSiH(2)SiH(2)OSO(2)CF(3) (5), which can be selectively converted into mixed alkyl-aryl-disilanes with LiR reagents, e.g. (n-Bu)SiH2SiH2(p-Tol), 6. The crystal structure of compound 2 has been determined by an X-ray diffraction study; it has a staggered trans-conformation with a crystallographic center of inversion.

  DOI：

  10.1016/0022-328x(96)06391-7