[Cd(2,5-dibenzoylterephthalate)(2,2′-bipyridine)] | 1426168-18-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cd(2,5-dibenzoylterephthalate)(2,2′-bipyridine)]
• CAS: 1426168-18-4
• 化学式: C₁₀H₈N₂*C₂₂H₁₂O₆*Cd
• 分子量: 640.931
• InChiKey: SKCOMXYQCPQVQB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.02
• 重原子数：
  41.0
• 可旋转键数：
  7.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  140.18
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 cadmium(II) nitrate tetrhydrate 、 2,5-dibenzoylterephthalic acid 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 73.0h， 以61%的产率得到[Cd(2,5-dibenzoylterephthalate)(2,2′-bipyridine)]
  参考文献：
  名称：

  Syntheses, structures, and luminescence of three metal carboxylate polymers of 2,5-dibenzoylterephthalic acid and N-donor auxiliary ligands

  摘要：

  Three coordination polymers, [CdL(2,2-bpy)] (1), [ZnL(phen)2] (2), and [ZnL(2,2-bpy)] (3) (H2L=2,5-dibenzoylterephthalic acid, 2,2-bpy=2,2-bipyridine, and phen=1,10-phenanthroline), were synthesized and crystallographically characterized. The compounds were further characterized by elemental analyses, FTIR, thermogravimetric analyses, and powder X-ray diffraction. Complex 1 exhibits a 2D sheet structure with (4,4) grid units, while 2 and 3 present infinite 1D zigzag chain structures. The complexes are all extended into high-dimensional supramolecular networks through intermolecular hydrogen bonds and stacking interactions. A structural comparison of 13 demonstrates that the characteristics of subsidiary ligands and slight difference in coordination models of L play a very important role in construction of the complexes. Additionally, luminescence of the complexes is also investigated at room temperature.

  DOI：

  10.1080/00958972.2012.752466