[(2,6-bis(trimethylsilyl)phenyl-S)Fe(2,6-di(mesityl)phenyl-S)] | 956243-42-8

• 英文名称: [(2,6-bis(trimethylsilyl)phenyl-S)Fe(2,6-di(mesityl)phenyl-S)]
• CAS: 956243-42-8
• 化学式: C₃₆H₄₆FeS₂Si₂
• 分子量: 654.911
• InChiKey: KYAVLZBYTBNLJF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  iron(II) bis(trimethylsilyl)amide 、 2,6-bis(trimethylsilyl)benzenethiol 、 2,6-bis(2,4,6-trimethylphenyl)phenylthiol 以 甲苯 为溶剂， 以56%的产率得到[(2,6-bis(trimethylsilyl)phenyl-S)Fe(2,6-di(mesityl)phenyl-S)]
  参考文献：
  名称：

  Synthesis and characterization of heteroleptic iron(II) thiolate complexes with weak iron–arene interactions

  摘要：

  Selective preparation and characterization of a series of heteroleptic thiolate complexes of iron(II) are described. The compounds were synthesized by treatment of iron bis-amide Fe{N(SiMe3)(2)}(2) (1) with 1 equiv. of terphenyl thiols HS(2,6-(aryl)(2)C6H3) followed by addition of another equivalent of different thiol. An amide-thiolate intermediate [{(Me3Si)(2)N}Fe](2)(mu-SDpp)(2) (2; Dpp = 2,6-Ph2C6H3) was isolated from the 1:1 reaction of I and HSDpp. The X-ray crystal structures of all new thiolate complexes have been determined. The compounds crystallize as monomers or dimers, dependent on the substituents. They consist of distorted tetrahedral or trigonal-pla nar iron centers with weak interactions between the aromatic rings of thiolate ligands, where the Fe-C(arene) contact is 2.272(2) A at shortest. The stronger iron-arene interaction appears to induce more pyramidalized geometry at the iron center. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.06.027