[Ru(2-mercaptopyridine(1-))2(cis-1,2-bis(diphenylphosphino)ethylene] | 553628-09-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Ru(2-mercaptopyridine(1-))2(cis-1,2-bis(diphenylphosphino)ethylene]
• CAS: 553628-09-4
• 化学式: C₃₆H₃₀N₂P₂RuS₂
• 分子量: 717.797
• InChiKey: KMXGUCLDHRPNSC-FAIYXUOWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(2-mercaptopyridinato)bis(triphenylphosphine)ruthenium(II) 、 1,2-bis(diphenylphosphino)ethylene 以 甲苯 为溶剂， 以76%的产率得到[Ru(2-mercaptopyridine(1-))2(cis-1,2-bis(diphenylphosphino)ethylene]
  参考文献：
  名称：

  Lobana, Tarlok S.; Verma, Renu, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2003, vol. 42, # 3, p. 534 - 536

  摘要：

  DOI：

文献信息

• Dependence of the product on the P–P ligand in reactions of [RuCl3(NO)(P–P)] complexes (P–P = aromatic diphosphines) with 2-mercaptopyridine
  作者：Gustavo Von Poelhsitz、André L. Bogado、Luciano M. Lião、Antonio G. Ferreira、Eduardo E. Castellano、Javier Ellena、Alzir A. Batista

  DOI：10.1016/j.poly.2009.09.004

  日期：2010.1

  This study presents the syntheses and characterization of 2-mercaptopyridine (pyS(-)) complexes containing ruthenium(II) with the following general formula [Ru(pyS)(2)(P-P)], P-P = (c-dppen) = cis-1,2-bis(diphenylphosphino)ethylene) (1); (dppe)=1,2-bis(diphenylphosphino)ethane (2); (dppp)=1,3-bis(diphenylphosphino)propane (3) and (dppb) = 1,4-bis(diphenylphosphino)butane (4). The complexes were synthesized from the mer- or fac-[RuCl3(NO)(P-P)] precursors in the presence of triethylamine in methanol solution with dependence of the product on the P-P ligand. The reaction of pyS- with a ruthenium complex containing a bulky aromatic diphosphine dppb disclosed a major product with a dangling coordinated dppbO-P, the [Ru(pyS)(2)(NO)(eta(1)-dppbO-P)]PF6 (5). In addition, this work also presents and discusses the spectroscopic and electrochemical behavior of 1-5. and report the X-ray structures for I and S. (C) 2009 Elsevier Ltd. All rights reserved.