anthracen-9-yl (2R)-2-methoxy-2-phenylacetate | 851512-34-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: anthracen-9-yl (2R)-2-methoxy-2-phenylacetate
• CAS: 851512-34-0
• 化学式: C₂₃H₁₈O₃
• 分子量: 342.394
• InChiKey: HKLYKJFSNDQJGJ-OAQYLSRUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  anthracen-9-yl (2R)-2-methoxy-2-phenylacetate 、 马来酸酐 生成
  参考文献：
  名称：

  A new, chiral aminoanthracene for the Diels–Alder/retro-Diels–Alder sequence in lactam and butenolide synthesis

  摘要：

  9-(2-Phenylethyl)aminoanthracene has been prepared and used as a template in the Diels-Alder/retro-Diels-Alder sequence to produce alpha,beta-butenolides and alpha,beta-unsaturated lactams. In this sequence the aminoanthracene serves as a stereo- and regiocontrolling chaperone in guiding maleic anhydride or N-alkylmaleimides through transformations to the butenolide or lactam targets. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.02.046
• 作为产物：
  描述：

  蒽酮 、 (R)-(-)-α-methoxyphenylacetyl chloride 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 生成 anthracen-9-yl (2R)-2-methoxy-2-phenylacetate
  参考文献：
  名称：

  A new, chiral aminoanthracene for the Diels–Alder/retro-Diels–Alder sequence in lactam and butenolide synthesis

  摘要：

  9-(2-Phenylethyl)aminoanthracene has been prepared and used as a template in the Diels-Alder/retro-Diels-Alder sequence to produce alpha,beta-butenolides and alpha,beta-unsaturated lactams. In this sequence the aminoanthracene serves as a stereo- and regiocontrolling chaperone in guiding maleic anhydride or N-alkylmaleimides through transformations to the butenolide or lactam targets. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.02.046