4,5,6,7-四溴-1,3-二氢-1,3-二(2-羟基乙基)-2H-苯并咪唑-2-酮 | 56315-67-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 中文名称: 4,5,6,7-四溴-1,3-二氢-1,3-二(2-羟基乙基)-2H-苯并咪唑-2-酮
• 英文名称: 1,3-Bis-(2-hydroxy-ethyl)-4,5,6,7-tetrabrom-benzimidazolon
• 英文别名: 4,5,6,7-tetrabromo-1,3-bis-(2-hydroxy-ethyl)-1,3-dihydro-benzoimidazol-2-one；4,5,6,7-tetrabromo-1,3-dihydro-1,3-bis(2-hydroxyethyl)-2H-benzimidazol-2-one；1,3-di-(2'-hydroxyethyl)-4,5,6,7-tetrabromobenzimidazolone；4,5,6,7-tetrabromo-1,3-bis(2-hydroxyethyl)benzimidazol-2-one
• CAS: 56315-67-4
• 化学式: C₁₁H₁₀Br₄N₂O₃
• 分子量: 537.828
• InChiKey: WKQKLCTYZKFNTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  64
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,3-二(2-羟基乙基)苯并咪唑-2-酮 在 溴 作用下， 以 N-甲基乙酰胺 、 active charcoal 、 水 、 异丙醇 为溶剂， 生成 4,5,6,7-四溴-1,3-二氢-1,3-二(2-羟基乙基)-2H-苯并咪唑-2-酮
  参考文献：
  名称：

  Halogen-substituted benzimidazolone compounds

  摘要：

  通过将N,N'-取代苯并咪唑酮与氯或溴反应，可以获得新的氯化和/或溴化N,N'-取代苯并咪唑酮。这些新的含氯和/或溴的苯并咪唑酮化合物适用于生产耐热、阻燃的聚合物。

  公开号：

  US03954790A1

文献信息

• Acid-sensitive leuco dye polymeric films
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0389113A2

  公开（公告）日：1990-09-26

  A color-change dosimeter film made of a halogen-containing polymer in which is dispersed an acid-sensitive leuco dye, which dye a) is substantially free from groups that are sensitive to high-energy radiation and b) becomes colored in acid. This color-change dosimeter film (1) remains substantially colorless upon exposure to artificial illumination, including fluorescent light, for at least several months, (2) becomes colored upon exposure to high-energy radiation and accurately indicates small changes in dosage by the intensity of its color, and (3) remains substantially unchanged in its intensity of that color after being stored for several months, whether or not exposed to artificial illumination. An article of either quantitative or qualitative determination of the extent of high-energy radiation exposure is also provided, displaying a colored message of words, codes, symbols, or patterns on a substrate after exposure to the high-energy radiation.

  一种变色剂量计薄膜，由一种含卤聚合物制成，其中分散有一种对酸敏感的leuco 染料，这种染料 a) 基本上不含对高能辐射敏感的基团，b) 在酸中会变色。这种变色剂量计胶片（1）在人工照明（包括荧光灯）下至少几个月保持基本无色；（2）在高能辐射下变色，并通过颜色强度准确显示剂量的微小变化；（3）在储存几个月后，无论是否在人工照明下，颜色强度基本保持不变。此外，还提供了一种可定量或定性确定高能辐射照射程度的物品，可在高能辐射照射后在基底上显示由文字、代码、符号或图案组成的彩色信息。
• Flammwidrige Kunststofformmasse
  申请人：CIBA-GEIGY AG

  公开号：EP0025018B1

  公开（公告）日：1985-05-29
• Polyesterformmassen verminderter Korrosionswirkung gegenüber Metallen und deren Verwendung
  申请人：CIBA-GEIGY AG

  公开号：EP0031792B1

  公开（公告）日：1985-07-31
• IN SITU MOISTURE GENERATION AND USE OF POLYFUNCTIONAL ALCOHOLS FOR CROSSLINKING OF SILANE-FUNCTIONALIZED RESINS
  申请人：Dow Global Technologies LLC

  公开号：EP2207851B1

  公开（公告）日：2015-11-25
• In Situ Moisture Generation and Use of Polyfunctional Alcohols for Crosslinking of Silane-Functionalized Resins
  申请人：Chaudhary Bharat I.

  公开号：US20100297374A1

  公开（公告）日：2010-11-25

  Polymer compositions comprise a (i) silane-functionalized polymer, e.g., a polyethylene grafted with vinyl triethoxy silane, (H) polyfunctional alcohol e.g., α,α,α′,α′˜tetramethyl-I,3-benzenediethanol and, optionally, (iii) acid, e.g., an alkylated aryl disulfonic acid. The use of polyfunctional alcohols in the absence of a strong acid yields a light-crosslinking of the silane-functionalized polymer and this, in turn, provides a polymer melt with improved extensional properties such as elongational viscosity and melt strength. The use of a polyfunctional alcohol in combination with a blocked strong acid provides a slow rate of crosslinking during melt processing and a high degree of ultimate crosslinking after the polymer composition has been shaped or molded.