Hexakis-(pentafluorphenyl)-benzol | 35525-35-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Hexakis-(pentafluorphenyl)-benzol
• 英文别名: Hexakis(pentafluorophenyl)benzol；1,2,3,4,5,6-Hexakis(2,3,4,5,6-pentafluorophenyl)benzene
• CAS: 35525-35-0
• 化学式: C₄₂F₃₀
• 分子量: 1074.41
• InChiKey: ZHGDMQOWRXQCNY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.7
• 重原子数：
  72
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  30

反应信息

• 作为产物：
  描述：

  1,2,3,4,5-五氟-6-[2-(2,3,4,5,6-五氟苯基)乙炔基]苯 在 铱 作用下， 生成 Hexakis-(pentafluorphenyl)-benzol
  参考文献：
  名称：

  Rausch,M.D.; Gastinger,R.G., Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1979, vol. 34, p. 700 - 705

  摘要：

  DOI：

文献信息

• FLUORINATED AROMATIC COMPOUND, METHOD FOR ITS PRODUCTION, CURABLE MATERIAL, ITS CURED PRODUCT, AND OPTICAL MEMBER
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US20160137572A1

  公开（公告）日：2016-05-19

  To provide a novel fluorinated aromatic compound having at least two carbon-carbon unsaturated bonds, a method for its production, a curable material comprising the fluorinated aromatic compound, a cured product thereof, and an optical member. The fluorinated aromatic compound is represented by formula (A), wherein n is an integer of 0 to 6, a is an integer of 0 to 5, b is an integer of 0 to 4, c is an integer of 0 to 4, a+c+n is 2 to 6, a+b is 2 to 9, Z is a single bond, —O—, —S—, —CO—, —C(CH 3 ) 2 —, —C(CF 3 ) 2 —, —SO—, or —SO 2 —, Rf 1 is a C 1-8 fluoroalkyl group, Y 1 and Y 2 are each independently a group represented by formula (1) (s is 0 or 1, and R 1 , R 2 , R 3 , and R 4 are each independently a hydrogen atom or a fluorine atom), and F in the aromatic ring indicates that hydrogen atoms in the aromatic ring are all substituted by fluorine atoms.

  提供一种至少具有两个碳-碳不饱和键的新型氟芳香化合物，一种其生产方法，包括所述氟芳香化合物的可固化材料，其固化产物以及光学部件。所述氟芳香化合物由式（A）表示，其中n为0至6的整数，a为0至5的整数，b为0至4的整数，c为0至4的整数，a+c+n为2至6，a+b为2至9，Z为单键，—O—，—S—，—CO—，—C(CH3)2—，—C(CF3)2—，—SO—，或—SO2—，Rf1为C1-8氟烷基，Y1和Y2分别独立地表示由式（1）表示的基团（s为0或1，R1、R2、R3和R4分别独立地表示氢原子或氟原子），芳香环中的F表示芳香环中的氢原子均被氟原子取代。
• FLUORINE-CONTAINING AROMATIC COMPOUND, METHOD FOR PRODUCING SAME, CURABLE MATERIAL, CURED PRODUCT THEREOF, AND OPTICAL MEMBER
  申请人：Asahi Glass Company, Limited

  公开号：EP3031793A1

  公开（公告）日：2016-06-15

  To provide a novel fluorinated aromatic compound having at least two carbon-carbon unsaturated bonds, a method for its production, a curable material comprising the fluorinated aromatic compound, a cured product thereof, and an optical member. The fluorinated aromatic compound is represented by formula (A), wherein n is an integer of 0 to 6, a is an integer of 0 to 5, b is an integer of 0 to 4, c is an integer of 0 to 4, a+c+n is 2 to 6, a+b is 2 to 9, Z is a single bond, -0-, -S-, -CO-, -C(CH3)2-, -C(CF3)2-, -SO-, or -SO2-, Rf1 is a C1-8 fluoroalkyl group, Y1 and Y2 are each independently a group represented by formula (1) (s is 0 or 1, and R1, R2, R3, and R4 are each independently a hydrogen atom or a fluorine atom), and F in the aromatic ring indicates that hydrogen atoms in the aromatic ring are all substituted by fluorine atoms.

  提供一种至少具有两个碳-碳不饱和键的新型含氟芳香族化合物、其生产方法、包含该含氟芳香族化合物的可固化材料、其固化产物以及光学部件。氟化芳香族化合物由式 (A) 表示，其中 n 是 0 至 6 的整数，a 是 0 至 5 的整数，b 是 0 至 4 的整数，c 是 0 至 4 的整数，a+c+n 是 2 至 6，a+b 是 2 至 9，Z 是单键、-0-、-S-、-CO-、-C(CH3)2-、-C(CF3)2-、-SO- 或-SO2-、Rf1 是 C1-8 氟烷基，Y1 和 Y2 各自独立地是式 (1) 所代表的基团（s 是 0 或 1，R1、R2、R3 和 R4 各自独立地是氢原子或氟原子），芳香环中的 F 表示芳香环中的氢原子全部被氟原子取代。
• FLUORINE-CONTAINING CROSSLINKABLE ELASTOMER COMPOSITION AND CROSSLINKED PRODUCT THEREOF
  申请人：Asahi Glass Company, Limited

  公开号：EP3031856A1

  公开（公告）日：2016-06-15

  To provide a crosslinkable fluorinated elastomer composition which is excellent in crosslinking reactivity and of which a crosslinked product is excellent in heat resistance and chemical resistance. The crosslinkable fluorinated elastomer composition comprises a fluorinated elastomer (e.g. a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer) and an aromatic compound having at least two crosslinkable unsaturated double bonds (e.g. a compound represented by the formula (A-1)), and the crosslinked product is one obtained by crosslinking the crosslinkable fluorinated elastomer composition.

  提供一种可交联含氟弹性体组合物，该组合物具有优异的交联反应性，其交联产品具有优异的耐热性和耐化学性。可交联含氟弹性体组合物由含氟弹性体（例如四氟乙烯/全氟（烷基乙烯基醚）共聚物）和至少具有两个可交联不饱和双键的芳香族化合物（例如由式（A-1）表示的化合物）组成，交联产物是通过交联该可交联含氟弹性体组合物获得的。
• Crosslinkable fluorinated elastomer composition and crosslinked product thereof
  申请人：Asahi Glass Company, Limited

  公开号：US10066077B2

  公开（公告）日：2018-09-04

  To provide a crosslinkable fluorinated elastomer composition which is excellent in crosslinking reactivity and of which a crosslinked product is excellent in heat resistance and chemical resistance. The crosslinkable fluorinated elastomer composition comprises a fluorinated elastomer (e.g. a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer) and an aromatic compound having at least two crosslinkable unsaturated double bonds (e.g. a compound represented by the formula (A-1)), and the crosslinked product is one obtained by crosslinking the crosslinkable fluorinated elastomer composition.

  提供一种可交联含氟弹性体组合物，该组合物具有优异的交联反应性，其交联产品具有优异的耐热性和耐化学性。可交联含氟弹性体组合物由含氟弹性体（例如四氟乙烯/全氟（烷基乙烯基醚）共聚物）和至少具有两个可交联不饱和双键的芳香族化合物（例如由式（A-1）表示的化合物）组成，交联产物是通过交联该可交联含氟弹性体组合物获得的。
• Fluorinated aromatic compound, method for its production, curable material, its cured product, and optical member
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US10087128B2

  公开（公告）日：2018-10-02

  To provide a novel fluorinated aromatic compound having at least two carbon-carbon unsaturated bonds, a method for its production, a curable material comprising the fluorinated aromatic compound, a cured product thereof, and an optical member. The fluorinated aromatic compound is represented by formula (A), wherein n is an integer of 0 to 6, a is an integer of 0 to 5, b is an integer of 0 to 4, c is an integer of 0 to 4, a+c+n is 2 to 6, a+b is 2 to 9, Z is a single bond, —O—, —S—, —CO—, —C(CH3)2—, —C(CF3)2—, —SO—, or —SO2—, Rf1 is a C1-8 fluoroalkyl group, Y1 and Y2 are each independently a group represented by formula (1) (s is 0 or 1, and R1, R2, R3, and R4 are each independently a hydrogen atom or a fluorine atom), and F in the aromatic ring indicates that hydrogen atoms in the aromatic ring are all substituted by fluorine atoms.

  提供一种至少具有两个碳-碳不饱和键的新型含氟芳香族化合物、其生产方法、包含该含氟芳香族化合物的可固化材料、其固化产物以及光学部件。氟化芳香族化合物由式 (A) 表示，其中 n 是 0 至 6 的整数，a 是 0 至 5 的整数，b 是 0 至 4 的整数，c 是 0 至 4 的整数，a+c+n 是 2 至 6，a+b 是 2 至 9，Z 是单键、-O-、-S-、-CO-、-C(CH3)2-、-C(CF3)2-、-SO- 或 -SO2-、Rf1 是 C1-8 氟烷基，Y1 和 Y2 各自独立地是式 (1) 所代表的基团（s 是 0 或 1，R1、R2、R3 和 R4 各自独立地是氢原子或氟原子），芳香环中的 F 表示芳香环中的氢原子全部被氟原子取代。