| 791124-21-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 791124-21-5
• 化学式: C₇H₈*C₅₅H₇₃FeN₃P₂Si₂
• 分子量: 1042.31
• InChiKey: OBFABOGQWFVTJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  iron(II) bis(trimethylsilyl)amide 、 甲苯 、 [2,6-Di(propan-2-yl)phenyl]imino-[[[2,6-di(propan-2-yl)phenyl]imino-diphenyl-lambda5-phosphanyl]methyl]-diphenyl-lambda5-phosphane 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Three-coordinate bis(phosphinimino)methanide derivatives of ‘open shell’ [M(II)] (M=Mn, Fe, Co) transition metals

  摘要：

  An alternative two-step synthesis of the previously reported bis(diphenylphosphinimino)methane [CH2(Ph2P = NC6H3'Pr-2-2,6)(2)] involving bromine oxidation of dppm and metathesis with 2,6-diisopropylaniline is described. [CH2(Ph2P=NC6H3' Pr-2-2,6)(2)] is readily deprotonated by the transition metal silylamides [M{N(SiMe3)(2)}(2)] (M = Mn, Fe and Co) to provide a series of exclusively three-coordinate derivatives [{CH(Ph2PNC6H3'Pr-2-2,6)(2)M {N(SiMe3)(2)}] which have been characterised by elemental analysis, magnetic measurements and, in the case of the Fe derivative, X-ray structural analysis. Reactivity studies have shown that even such sterically demanding bis(phosphinimino)methanide ligands are prone to protonolysis and reductive [P(V) to P(III)] degradation which limits their utility as stable platforms for further M(II) derivitisation. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.050