Phosphorsaeure-mono-benzyl-thioester | 46119-77-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phosphorsaeure-mono-benzyl-thioester
• 英文别名: Benzylsulfanylphosphonic acid
• CAS: 46119-77-1
• 化学式: C₇H₉O₃PS
• 分子量: 204.186
• InChiKey: ORUGPWKFNPKJGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  82.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  溴甲苯 生成 Phosphorsaeure-mono-benzyl-thioester
  参考文献：
  名称：

  Zwierzak,A.; Gramze,R., Zeitschrift fur Naturforschung. Teil B: Chemie, Biochemie, Biophysik, Biologie, 1971, vol. 26, p. 386 - 388

  摘要：

  DOI：

文献信息

• [EN] UNNATURAL POLYMERASE SUBSTRATES THAT CAN SUSTAIN ENZYMATIC SYNTHESIS OF DOUBLE STRANDED NUCLEIC ACIDS FROM A NUCLEIC ACID TEMPLATE AND METHODS OF USE<br/>[FR] SUBSTRATS NON NATURELS POUR POLYMÉRASES POUVANT SUPPORTER LA SYNTHÈSE ENZYMATIQUE D'ACIDES NUCLÉIQUES DOUBLE BRIN À PARTIR D'UNE MATRICE D'ACIDE NUCLÉIQUE ET PROCÉDÉS D'UTILISATION
  申请人：LIFE TECHNOLOGIES

  公开号：WO2009134469A1

  公开（公告）日：2009-11-05

  Nucleotide analogs that can sustain the enzymatic synthesis of double-stranded nucleic acid from a nucleic template are described. The nucleotide analogs include: (i) a base selected from the group consisting of adenine, guanine, cytosine, thymine, uracil and their analogs; (ii) a label attached to the base or analog of the base via a cleavable linker; (iii) a deoxyribose; and (iv) one or more phosphate groups. The linker and/or the label inhibits template directed polymerase incorporation of a further nucleotide substrate onto an extended primer strand. In addition, cleavage of the linker leaves a residue attached to the base which is not present in the natural nucleotide and which does not inhibit extension of the primer strand. The nucleotide analogs can therefore be used as reversible terminators in sequencing by synthesis methods without blocking the 3' hydroxyl group. Methods of sequencing DNA using the substrates are also described.

  描述了可以维持从核酸模板中酶催化合成双链核酸的核苷酸类似物。核苷酸类似物包括：（i）从腺嘌呤、鸟嘌呤、胞嘧啶、胸腺嘧啶、尿嘧啶及其类似物组成的碱基；（ii）通过可裂解连接物连接到碱基或碱基类似物上的标签；（iii）脱氧核糖；以及（iv）一个或多个磷酸基团。连接物和/或标签抑制模板定向聚合酶在扩展引物链上进一步催化合成核苷酸底物。此外，连接物的裂解留下一个残基连接到碱基上，该残基不在天然核苷酸中存在，也不会抑制引物链的扩展。因此，可以将核苷酸类似物用作合成中可逆的终止子，而不会阻塞3'羟基。还描述了使用这些底物测序DNA的方法。
• Oil additive concentrates and lubricants of enhanced performance capabilities
  申请人：ETHYL PETROLEUM ADDITIVES LIMITED

  公开号：EP0531585A1

  公开（公告）日：1993-03-17

  Additive concentrates, lubricating oil compositions and the use thereof are described. The compositions comprise one or more of each of the following oil-soluble additive components: a) a Mannich base ashless dispersant; b) a metal-free sulphur-containing antiwear and/or extreme pressure agent; c) a metal-free phosphorus-containing and nitrogen-containing antiwear and/or extreme pressure agent; and optionally but preferably, d) an amine salt of a carboxylic acid. Oils containing such additive components exhibit excellent performance under heavy duty service such as in the planetary spur gear test. In addition, such oils exhibit good demulsibility in the ASTM D1401 test procedure and good clean gear performance in the CRC L-60 test.

  本文描述了添加剂浓缩物、润滑油组合物及其用途。这些组合物包含以下每种油溶性添加剂成分中的一种或多种：a) 曼尼希基无灰分散剂；b) 不含金属的含硫抗磨剂和/或极压剂；c) 不含金属的含磷和含氮抗磨剂和/或极压剂；以及可选但最好是 d) 羧酸胺盐。含有此类添加剂成分的机油在重负荷工作（如行星直齿轮试验）中表现出卓越的性能。此外，此类润滑油在 ASTM D1401 试验程序中表现出良好的抗乳化性，在 CRC L-60 试验中表现出良好的清洁齿轮性能。
• USE OF FATTY ALCOHOL CARBONATES AS SOLVENTS IN AGRICULTURAL FORMULATIONS
  申请人：Cognis Corporation

  公开号：EP1035770A1

  公开（公告）日：2000-09-20
• EP1035770A4
  申请人：——

  公开号：EP1035770A4

  公开（公告）日：2002-07-24
• AGRICULTURAL ADJUVANT
  申请人：Cognis Corporation

  公开号：EP1037528A1

  公开（公告）日：2000-09-27