acetylacetonato-[[[bis[2,4-di-tert-butylphenoxy]phosphino-P]oxy]-3,5-di-tert-butylphenyl-C]palladium(II) | 947519-27-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: acetylacetonato-[[[bis[2,4-di-tert-butylphenoxy]phosphino-P]oxy]-3,5-di-tert-butylphenyl-C]palladium(II)
• CAS: 947519-27-9
• 化学式: C₄₇H₆₉O₅PPd
• 分子量: 851.456
• InChiKey: VNUWSHFNLXJIBI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  di(μ-acetato)-bis[2-[[bis[2,4-di-tert-butylphenoxy]phosphino-κP]oxy]-3,5-di-tert-butylphenyl-κC]dipalladium(II)*tetrahydrofuran 、 乙酰丙酮 以 二氯甲烷 为溶剂， 以96.6%的产率得到acetylacetonato-[[[bis[2,4-di-tert-butylphenoxy]phosphino-P]oxy]-3,5-di-tert-butylphenyl-C]palladium(II)
  参考文献：
  名称：

  Preparation of NHC-substituted phosphitepalladacycles

  摘要：

  The preparation of unsaturated NHC-substituted phosphitepalladacycles via phosphitepalladacycle acetato and chloro precursors and azoliurn salts with non-coordinating anions in DMSO is reported. With this one-pot synthesis NHC-substituted phosphitepalladacycles are obtained avoiding multi-step reactions. The molecular structures of an acetate-bridged phosphitepalladacycle dimer, an unsaturated NHC-substituted palladacyclic complex and one acetylacetonato phosphapalladacycle complex have been determined by single-crystal X-ray analysis. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.03.020