4-amino-3-anilino-6-methyl-1,2,4-triazin-5-one;dichlororuthenium;1-methyl-4-propan-2-ylbenzene | 168206-05-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-amino-3-anilino-6-methyl-1,2,4-triazin-5-one;dichlororuthenium;1-methyl-4-propan-2-ylbenzene
• CAS: 168206-05-1
• 化学式: C₂₀H₂₅ClN₅ORu*Cl
• 分子量: 523.427
• InChiKey: AQNOAXIDFNVNBJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 4-amino-6-methyl-5-oxo-3-phenyl-amino-4,5-dihydro-1,2,4-triazine 以 二氯甲烷 为溶剂， 以70%的产率得到4-amino-3-anilino-6-methyl-1,2,4-triazin-5-one;dichlororuthenium;1-methyl-4-propan-2-ylbenzene
  参考文献：
  名称：

  Preparation and study of functionalized 1,2,4-triazine derivatives of the (η6-arene)RuII (arene = benzene or p-cymene) and (η5-C5Me5)RhIII moieties

  摘要：

  In dichloromethane the complexes [{(eta(6)-arene)RuCl(mu-Cl)}(2)] (arene = benzene or p-cymene) and [{(eta(5)-C(5)Me(5)) RhCl(mu-Cl)}(2)] react with the triazines 4-amino-6-methyl-5-oxo-3 -thioxo-2,3,4, 5-tetrahydro-1,2,4-triazine (3-S-ATAZ), 4-amino-6-methyl-5-oxo-3-phenylamino-4,5-dihydro-1,2,4-triazine (3-PhNH-ATAZ) and 4-amino-6-methyl-5-oxo-3-amino-4,5-dihydro- 1,2,4-triazine (3-NH2-ATAZ) to form the corresponding complexes [(eta(6)-arene) RuCl(triazine)]Cl and [(eta(5)-C(5)Me(5)) RhCl(triazine)]Cl. The new compounds have been characterized by conductance measurements and spectroscopic (IR,H-1, C-13)methods. In every case the triazine acts as a chelating bidentate ligand, which has been confirmed by a single-crystal diffraction study carried out with [(eta(5)-C(5)Me(5)) RhCl(3-PhNH-ATAZ)]PF6 . H2O.

  DOI：

  10.1016/0277-5387(94)00469-u