Zn(5-(2-pyridyl)-1,3,4-oxadiazole-2-thionate)2(H2O)2 | 953794-00-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Zn(5-(2-pyridyl)-1,3,4-oxadiazole-2-thionate)2(H2O)2
• CAS: 953794-00-8
• 化学式: C₁₄H₁₂N₆O₄S₂Zn
• 分子量: 457.809
• InChiKey: ZNNDZTWZACFOOG-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  zinc(II) sulfate heptahydrate 、 5-(吡啶-2-基)-1,3,4-噁二唑-2-硫醇 以 甲醇 、 水 为溶剂， 以75%的产率得到Zn(5-(2-pyridyl)-1,3,4-oxadiazole-2-thionate)2(H2O)2
  参考文献：
  名称：

  Radius-dependent assembly of complexes with the rigid unsymmetric ligand 5-(2-pyridyl)-1,3,4-oxadiazole-2-thione: Syntheses, structures and luminescence properties

  摘要：

  The free ligand, 5-(2-pyridyl)-1,3,4-oxadiazole-2-thione (1, HL5), has been synthesized and characterized; its three new functional d1o transition-metal complexes, [Zn(L5)(2)(H2O)(2)] (2), [Cd(L5)2](n) (3) and [Hg-2(L5)(4)] (4), have been successfully obtained by a diffusion synthetic method and characterized by single-crystal X-ray diffraction, infrared spectroscopy, elemental analysis, thermogravimetric analysis, and photoluminescence. On the basis of the X-ray analyses, the radii of the metal ions are found to play an important role in determining the structures. The radii and nature of the metal ions can impart their influence on the coordination geometry of the d(10) transition-metal atoms, which seems to be the main factor controlling the structures and luminescent properties of the reaction products in this system. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.06.026