| 1114592-61-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1114592-61-8
• 化学式: C₃₀H₃₉NO₅S₃
• 分子量: 589.841
• InChiKey: SPOXKJUVYSKZPO-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 4,7,13,16,21,24-六氧-1,10-二氮双环[8.8.8]二十六烷 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Two mononuclear Tc complexes: [2,2′-(3-phenylpropylimino)- and [2,2′-(propylimino)bis(ethanethiolato)](4-methoxybenzenethiolato)oxidotechnate(V)

  摘要：

  The molecular structures of the two mononuclear title complexes, namely (4-methoxybenzenethiolato-kappa S) oxido[2,2'-(3-phenylpropylimino)bis(ethanethiolato)-kappa S-3,N,S']technetium(V), [Tc(C14H21NS2)(C7H7OS)O], (I), and (4-methoxybenzenethiolato kappa S) oxido[2,2'-( propylimino) bis(ethanethiolato)-kappa S-3,N,S'] technetium(V), [Tc(C7H15NS2)(C7H7OS)O], (II), exhibit the same coordination environment for the central Tc atoms. The atoms are five-coordinated (TcNOS3) with a square-pyramidal geometry comprising a tridentate 2,2'-(3-phenylpropylimino) bis(ethanethiolate) or 2,2'-(propylimino) bis(ethanethiolate) ligand, a 4-methoxybenzenethiolate ligand and an additional oxide O atom. Intermolecular C H center dot center dot center dot O and C-H center dot center dot center dot S hydrogen bonds between the monomeric units result in two-dimensional layers with a parallel arrangement.

  DOI：

  10.1107/s0108270107052870