N-ferrocenyl-N'-tert.butyl sulfurdiimide | 182232-40-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: N-ferrocenyl-N'-tert.butyl sulfurdiimide
• 英文别名: tert-butylimino(cyclopenta-2,4-dien-1-ylimino)-λ4-sulfane;cyclopenta-1,3-diene;iron(2+)
• CAS: 182232-40-2
• 化学式: C₁₄H₁₈FeN₂S
• 分子量: 302.223
• InChiKey: LMIOJNFXPANLGN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  N-ferrocenyl-N'-tert.butyl sulfurdiimide 、 水 以 not given 为溶剂， 生成 aminoferrocene 、 ferrocenyl sulfinylimide
  参考文献：
  名称：

  Ferrocenyl Sulfinylimide and Diferrocenyl Sulfurdiimide, Fc?NSO and Fc(NSN)Fc

  摘要：

  AbstractAbbreviations and Nomenclature: Fc = η1‐ferrocenyl, CpFe(C5H4‐); Cp = η5‐cyclopentadienyl, η5‐C5H5. Compounds containing the —NSO group are designated as either thionylimides, sulfinylimides or N‐sulfinylamines. The systematic name is imido oxo sulfuranes(IV). The reactions of ferrocenylamine, FcNH2 (1), with thionyl chloride and sulfur dichloride in hexane solution in the presence of triethylamine lead to the title compounds FcNSO (2) and Fc(NSN)Fc (3), respectively, 2 and 3 have also been obtained in reactions of the silylated ferrocenylamine, FcNH(SiMe3) (1b), with thionyl chloride. The ferrocenyl sulfinylimide 2 has been converted to sulfurdiimides such as Fc(NSN)Fc (3) and Fc(NSN)R (R = tBu (4a), SiMe3 (4b)) by reaction with the lithium derivative of silylated amines, LiN(SiMe3)R (R = Fc, tBu, SiMe3). The new ferrocenyl compounds 2–4 have been characterized by their NMR spectra, and their electrochemical behaviour has been studied. The molecular structure of FcNSO (2) has been determined by an X‐ray structure analysis; the sulfinylimide has the Z configuration, and the —NSO group is coplanar with the cyclopentadienyl ring to which it is attached.

  DOI：

  10.1002/zaac.19966220913
• 作为产物：
  描述：

  、 2-甲基-2-(亚磺酰氨基)丙烷 以 not given 为溶剂， 生成 N-ferrocenyl-N'-tert.butyl sulfurdiimide
  参考文献：
  名称：

  Ferrocenyl Sulfinylimide and Diferrocenyl Sulfurdiimide, Fc?NSO and Fc(NSN)Fc

  摘要：

  AbstractAbbreviations and Nomenclature: Fc = η1‐ferrocenyl, CpFe(C5H4‐); Cp = η5‐cyclopentadienyl, η5‐C5H5. Compounds containing the —NSO group are designated as either thionylimides, sulfinylimides or N‐sulfinylamines. The systematic name is imido oxo sulfuranes(IV). The reactions of ferrocenylamine, FcNH2 (1), with thionyl chloride and sulfur dichloride in hexane solution in the presence of triethylamine lead to the title compounds FcNSO (2) and Fc(NSN)Fc (3), respectively, 2 and 3 have also been obtained in reactions of the silylated ferrocenylamine, FcNH(SiMe3) (1b), with thionyl chloride. The ferrocenyl sulfinylimide 2 has been converted to sulfurdiimides such as Fc(NSN)Fc (3) and Fc(NSN)R (R = tBu (4a), SiMe3 (4b)) by reaction with the lithium derivative of silylated amines, LiN(SiMe3)R (R = Fc, tBu, SiMe3). The new ferrocenyl compounds 2–4 have been characterized by their NMR spectra, and their electrochemical behaviour has been studied. The molecular structure of FcNSO (2) has been determined by an X‐ray structure analysis; the sulfinylimide has the Z configuration, and the —NSO group is coplanar with the cyclopentadienyl ring to which it is attached.

  DOI：

  10.1002/zaac.19966220913