| 1005770-37-5

• CAS: 1005770-37-5
• 化学式: C₈₄H₁₀₂N₆O₂₅Zn₇
• 分子量: 2053.49
• InChiKey: DGKSLJMBPMQCMS-RXDONPEOSA-B

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 sodium acetate 以 N,N-二甲基甲酰胺-d7 为溶剂， 生成
  参考文献：
  名称：

  Zinc Carboxylate Cluster Formation in Conjugated Metallomacrocycles:  Evidence for Templation

  摘要：

  A new [3 + 3] Schiff base macrocycle incorporating three N2O2 salphen-type binding sites and peripheral neopentyloxy substituents has been prepared. The incorporation of Zn2+ ions into this and related conjugated Schiff base macrocycles has been studied by NMR spectroscopy, mass spectrometry, and X-ray diffraction. When reacted with 7 equiv of zinc acetate, the macrocycles template the formation of heptanuclear complexes. Two tetranuclear Zn2+ complexes that are plausible intermediates in the assembly of the heptanuclear complexes have been isolated and structurally characterized. These reactive intermediates are promising substrates for the synthesis of polynuclear, mixed-metal clusters. We also demonstrate that this chemistry may be generalized to other bridging carboxylate ligands, such as methacrylate.

  DOI：

  10.1021/ic701385m