1,8-bis(2-benzoylethenyl)triptycene | 175468-90-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,8-bis(2-benzoylethenyl)triptycene
• CAS: 175468-90-3
• 化学式: C₃₈H₂₆O₂
• 分子量: 514.623
• InChiKey: XBBYZICZCLJODA-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  1,8-bis(2-benzoylethenyl)triptycene 在 三氟化硼乙醚 作用下， 反应 3.0h， 生成
  参考文献：
  名称：

  Preparations and Spin-spin Interactions of 4,4′-(Triptycene-1,8-diyl)bis(1-methyl-2,6-diphenylpyridinyl) Diradical and Its 1,5-Diyl Isomer

  摘要：

  4,4′-(Triptycene-1,8-diyl)bis(1-methyl-2,6-diphenylpyridinyl)diradical was prepared by 3%-Na-Hg reduction of the corresponding dication and the ground state was estimated to be triplet or singlet with small S-T energy gap (< 20 J mol−1). No triplet signal was observed under the similar conditions for the corresponding 1,5-diyl derivative.

  DOI：

  10.1246/cl.1996.169
• 作为产物：
  描述：

  苯甲酰基亚甲基三苯基膦 、 1,8-diformyltriptycene 以90%的产率得到1,8-bis(2-benzoylethenyl)triptycene
  参考文献：
  名称：

  Preparations and Spin-spin Interactions of 4,4′-(Triptycene-1,8-diyl)bis(1-methyl-2,6-diphenylpyridinyl) Diradical and Its 1,5-Diyl Isomer

  摘要：

  4,4′-(Triptycene-1,8-diyl)bis(1-methyl-2,6-diphenylpyridinyl)diradical was prepared by 3%-Na-Hg reduction of the corresponding dication and the ground state was estimated to be triplet or singlet with small S-T energy gap (< 20 J mol−1). No triplet signal was observed under the similar conditions for the corresponding 1,5-diyl derivative.

  DOI：

  10.1246/cl.1996.169