Cd(N-methyl-N-phenyldithiocarbamate)(N-ethyl-N-phenyldithiocarbamate) | 1269783-21-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cd(N-methyl-N-phenyldithiocarbamate)(N-ethyl-N-phenyldithiocarbamate)
• CAS: 1269783-21-2
• 化学式: C₈H₈NS₂*C₉H₁₀NS₂*Cd
• 分子量: 491.017
• InChiKey: ZEBOBMKCTKPFTF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  24.0
• 可旋转键数：
  3.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  aqueous cadmium chloride 、 sodium N-ethyl-N-phenyldithiocarbamate 、 sodium N-methyl-N-phenyldithiocarbamate 以 水 为溶剂， 以78.37%的产率得到Cd(N-methyl-N-phenyldithiocarbamate)(N-ethyl-N-phenyldithiocarbamate)
  参考文献：
  名称：

  Synthesis of hexadecylamine capped nanoparticles using group 12 complexes of N-alkyl-N-phenyl dithiocarbamate as single-source precursors

  摘要：

  Metal complexes of the type (MLL2)-L-1 [M = Zn, Cd, Hg; L-1 = N-methyl-N-phenyldithiocarbamato and L-2 = N-ethyl-N-phenyldithiocarbamato] have been synthesized and characterized by elemental analyses, FT-IR and NMR spectroscopy. The complexes are formulated as four coordinate species with the dithiocarbamates acting as bidentate chelating ligands. The complexes were thermolysed and used as single-source precursors for the synthesis of HDA-capped MS (M = Zn, Cd, Hg) nanoparticles. The HgS nanoparticles show a narrow size distribution from their TEM images, while the CdS nanoparticles gave crystalline particles with a sharp band absorption edge and a narrow PL band. The ZnS nanoparticles gave crystalline particles with a stacking arrangement. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.10.023

文献信息

• Synthesis, structural characterization, and thermal stability studies of heteroleptic cadmium(II) dithiocarbamate with different pyridyl groups
  作者：Damian C. Onwudiwe、Eric C. Hosten

  DOI：10.1016/j.molstruc.2017.09.076

  日期：2018.1

  structure presents a cadmium atom coordinated by two sulphur atoms of a dithiocarbamate ligand and two nitrogen atoms of the 2,2′-bipyridine to form a CdS 4 N 2 fragment, thus giving the structure around the Cd atom a distorted trigonal prism geometry. Complex 3 contains two discrete monomeric molecules of (phenanthroline) ( N , N –methyl phenyl– N , N –ethyl phenyl dithiocarbamato)cadmium (II) per unit cell

  摘要 镉的三种氯仿溶剂化加合物与 N-烷基-N-苯基二硫代氨基甲酸酯和吡啶、2,2-联吡啶和 1, 10 菲咯啉的混合配体的合成、表征和晶体结构，表示为 [CdL 1 L 2 (py) 2 ]·CHCl 3 (1) 、[CdL 1 L 2 bpy]∙CHCl 3 (2) 和[CdL 1 L 2 phen]∙CHCl 3 (3) (LI = N-甲基-N-苯基二硫代氨基甲酸酯，L 2 =分别报道了 N-乙基-N-苯基二硫代氨基甲酸酯、py = 吡啶、bpy = 2,2-联吡啶和 phen = 1,10-菲咯啉)。配合物 1 在单斜空间群 P-1 中结晶，是一种中心对称的二聚体结构，其中每个 Cd 中心与两个单齿吡啶、一个双齿末端二硫代氨基甲酸酯和另一个双齿桥接二硫代氨基甲酸酯以形成四元环。配合物 2 在单斜空间群 P 2 1 / c 中结晶，在不对称单元中有四个离散的单体分子。该结构呈现由二硫代氨基甲酸酯配体的两个硫原子和2