| 159095-51-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 159095-51-9
• 化学式: C₅₈H₅₇N₄Rh
• 分子量: 913.023
• InChiKey: CSZMOWZMZPHGBC-YKKPBKTHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (5,10,15,20-tetraphenylporphyrinato)rhodium(III) chloride 、 tetradecylmagnesium bromide 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Action of alkyl halides on homo- and heteroporphyrin dimers involving a rhodium-indium bond, producing porphyrin complexes containing metal-carbon and metal-halide bonds

  摘要：

  The reactivity of the novel family of metalloporphyrin dimers containing a Rh-In bond towards alkyl halides is presented. The chemical reactivity of the homoleptic (same porphyrin ligand) and heteroleptic (different porphyrin ligand) porphyrin complexes with Rh-In metal-metal bond has been examined by photo- and thermal-processes in the presence of alkyl halides under anaerobic conditions in the dark. The photolytic and thermal reactions have been studied to define the polarity of the Rh-In single bond, as well as to identify the products. The presence of complexes containing Rh-C bonds in the reaction mixture detected by UV-vis spectroscopy postulated the formulation Rh(I)(-): --> In(III)(+) for the polarity of the metal-metal bond. In order to characterize the products we compare our spectroscopic results with those of the literature and those of authentic Rh-C containing complexes.

  DOI：

  10.1016/s0277-5387(00)88149-8