1,3-dipentyl-1,2,3,4-tetrahydrobenzo[g]pteridine-2,4-dione | 91921-23-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 蝶啶及其衍生物
• 英文名称: 1,3-dipentyl-1,2,3,4-tetrahydrobenzo[g]pteridine-2,4-dione
• 英文别名: 1,3-Dipentylbenzo[g]pteridine-2,4(1H,3H)-dione；1,3-dipentylbenzo[g]pteridine-2,4-dione
• CAS: 91921-23-2
• 化学式: C₂₀H₂₆N₄O₂
• 分子量: 354.452
• InChiKey: AFVMQJQLVIPCST-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  66.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-溴戊烷 、 alloxazine disodium salt 以 N,N-二甲基甲酰胺 为溶剂， 反应 20.0h， 以25%的产率得到1,3-dipentyl-1,2,3,4-tetrahydrobenzo[g]pteridine-2,4-dione
  参考文献：
  名称：

  Ring contraction of 1,3-bis(5-bromopentyl)alloxazine

  摘要：

  The reaction of 1,3-bis(5-bromopentyl)alloxazine with ethylamine in propan-2-ol resulted in replacement of the terminal bromine atoms by ethylamino groups and was accompanied by contraction of the pyrimidine ring so that the products were 1,3-bis[5-(ethylamino)pentyl]alloxazine and 1,3-bis[5-(ethylamino)-pentyl]imidazo[4,5-b]quinoxalin-2-one.

  DOI：

  10.1134/s1070428010030243

文献信息

• IMAGE-FORMING PHOTO-SENSITIVE MATERIAL
  申请人：SONY CORPORATION

  公开号：EP0105382A1

  公开（公告）日：1984-04-18

  An image-forming photo-sensitive material utilizing changes in adherence due to light, wherein an alloxazine derivative represented by the following formula (I), (wherein R's may be the same or different from each other and each represents an alkyl group containing 1 to 20 carbon atoms or a phenylalkyl group represented by the formula (II), (wherein n represents an integer of 1 or above)) is used as a photopolymerization initiator. In order to enable the photo- sensitive material to reproduce intermediate gradation of an image, the photo-sensitive material is provided with a composite structure wherein a photo-sensitive layer additionally containing a tertiary amine as a sensitizer is provided on a hardened layer formed by hardening a photo-sensitive composition. This photo-sensitive material can be used as a copying material for recording and reproducing a picture image from a cathode ray tube or a fiber tube.

  一种利用光引起的附着力变化形成图像的感光材料，其中由下式(I)代表的烯丙基嗪衍生物（式中R可以相同或不同，且各代表含有1至20个碳原子的烷基或由式(II)代表的苯基烷基（式中n代表1或以上的整数））被用作光聚合引发剂。为了使感光材料能够再现图像的中间层次，感光材料具有复合结构，即在通过硬化感光组合物而形成的硬化层上，提供额外含有叔胺作为敏化剂的感光层。这种感光材料可用作复印材料，用于记录和再现阴极射线管或纤维管中的图像。
• Ring contraction of 1,3-bis(5-bromopentyl)alloxazine
  作者：V. E. Semenov、R. Kh. Giniyatullin、D. R. Sharafutdinova、V. S. Reznik

  DOI：10.1134/s1070428010030243

  日期：2010.3

  The reaction of 1,3-bis(5-bromopentyl)alloxazine with ethylamine in propan-2-ol resulted in replacement of the terminal bromine atoms by ethylamino groups and was accompanied by contraction of the pyrimidine ring so that the products were 1,3-bis[5-(ethylamino)pentyl]alloxazine and 1,3-bis[5-(ethylamino)-pentyl]imidazo[4,5-b]quinoxalin-2-one.