tetrakis(trimethylphosphine)cobalt(I) tetraphenylborate | 53432-11-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetrakis(trimethylphosphine)cobalt(I) tetraphenylborate
• 英文别名: [Co(PMe3)4](tetraphenylborate)
• CAS: 53432-11-4
• 化学式: C₁₂H₃₆CoP₄*C₂₄H₂₀B
• 分子量: 682.54
• InChiKey: IQXQVCBKIRXDHY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.49
• 重原子数：
  42.0
• 可旋转键数：
  8.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  tetrakis(trimethylphosphine)cobalt(I) tetraphenylborate 在 paraformaldehyde 作用下， 以 四氢呋喃 、 水 为溶剂， 生成
  参考文献：
  名称：

  Pérès, Yolande; Dartiguenave, Michèle; Dartiguenave, Yves, Organometallics, 1990, vol. 9, # 4, p. 1041 - 1047

  摘要：

  DOI：
• 作为产物：
  描述：

  bromotris(trimethylphosphane)cobalt(I) 、 四苯硼钠 以 甲醇 为溶剂， 生成 tetrakis(trimethylphosphine)cobalt(I) tetraphenylborate
  参考文献：
  名称：

  Carvalho, L. C. Ananias de; Peres, Yolande; Dartiguenave, Michele, Acta Crystallographica, Section C: Crystal Structure Communications, 1989, vol. 45, p. 159 - 161

  摘要：

  DOI：

文献信息

• Dufour; Dartiguenave; Dartiguenave, Organometallics, 1990, vol. 9, # 10, p. 2832 - 2836
  作者：Dufour、Dartiguenave、Dartiguenave、Dubac

  DOI：——

  日期：——
• Synthesis, Structure, Spectroscopy, and Reactivity of Oxapentadienyl−Cobalt−Phosphine Complexes^,
  作者：John R. Bleeke、Bryn L. Lutes、Michael Lipschutz、Donastas Sakellariou-Thompson、John Seonghyun Lee、Nigam P. Rath

  DOI：10.1021/om100361a

  日期：2010.11.8

  The first examples of oxapentadienyl-cobalt complexes have been synthesized and structurally characterized. Treatment of (Cl)Co(PMe3)(3) with potassium oxapentadienide produces ((1,2,3-eta)-5-oxapentadienyl)Co(PMe3)(3) (1), while the reaction of (Cl)Co(PMe3)(3) with potassium 2,4-dimethyloxapentadienide generates ((1,2,3-eta)-2,4-dimethyl-5-oxapentadienyl)Co(PMe3)(3) (2). Both 1 and 2 undergo ligand substitution reactions when treated with excess carbon monoxide. Compound 1 reacts with 1 equiv of CO to produce ((1,2,3-eta)-5-oxapentadienyl)Co(PMe3)(2)(CO) (3), while 2 undergoes a double CO substitution to generate ((1,2,3-eta)-2,4-dimethyl-5-oxapentadienyl)Co(PMe3)(CO)(2) (4). Compound 3 can also be synthesized by reacting (Cl)Co(PMe3)(2)(CO)(2) with potassium oxapentadienide, but the analogous reaction involving potassium 2,4-dimethyloxapentadienide results in reduction of the cobalt starting material and production of the Co(0) dimer (CO)(PMe3)(2)Co(PMe)(2)Co(PMe3)(2)(Co) (5). Treatment of 1 with triflic acid (HO3SCF3) or methyl triflate (MeO3SCF3) results in electrophilic attack at oxygen and production of (eta(4)-butadienol)Co(PMe3)(3)+O3SCF3- (6) or (eta(4)-butadienyl methyl ether)Co(PMe3)3+O3SCF3- (7). Treatment of 2 with triflic acid or methyl triflate also results in electrophilic attack at oxygen; however, these products are unstable and rapidly lose their protonated or methylated ligands. The resulting Co(PMe3)4+O3SCF3-, generated in situ, reacts with excess carbon monoxide to produce Co(PMe3)(3)(CO)(2)+O3SCF3- (8). Compounds 1-8 have been characterized by single-crystal X-ray diffraction.
• (Trimethylphosphine)cobalt(I) complexes. 1. Reactivity with ethylene and crystal structure, [Co(MeCN)(C2H4)(PMe3)3]BPh4.MeCN
  作者：Brigitte Capelle、Andre L. Beauchamp、Michele Dartiguenave、Yves Dartiguenave、Hans Friedrich Klein

  DOI：10.1021/ja00378a018

  日期：1982.7
• (Trimethylphosphine)cobalt(I) complexes. 3. Bis(trimethylphosphine)cobalt tetraphenylborate, the first structural example of tetraphenylborate anion .pi.-coordinated to a first-row metal ion
  作者：L. Carlos Ananias de Carvalho、Michele Dartiguenave、Yves Dartiguenave、Andre L. Beauchamp

  DOI：10.1021/ja00334a067

  日期：1984.10