[U(diethylamide)3(tetrahydrofuran)3]BPh4 | 169622-17-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [U(diethylamide)3(tetrahydrofuran)3]BPh4
• CAS: 169622-17-7
• 化学式: C₂₄H₂₀B*C₂₄H₅₄N₃O₃U
• 分子量: 989.974
• InChiKey: TVMGNNDTUSCHOJ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [U(diethylamide)3(tetrahydrofuran)3]BPh4 以 neat (no solvent) 为溶剂， 生成 [U(diethylamide)3]BPh₄
  参考文献：
  名称：

  Synthesis of cationic uranium compounds by protonolysis of amide precursors: amide and chloroamide complexes

  摘要：

  The chloroamide compounds [U(NEt(2))Cl-3(thf)] and [U(NEt(2))(2)Cl-2] were isolated from the comproportionation reactions of [U(NEt(2))(4)] and UCl4 in tetrahydrofuran (thf) and were converted respectively into the cationic derivatives [UCl3(thf)(2)]BPh(4) and [U(NEt(2))Cl-2(thf)(2)] BPh(4) by treatment with NHEt(3)BPh(4). Protonolysis of [U(NEt(2))(4)] afforded the monocation [U(NEt(2))(3)](+) which was itself transformed into the dication [U(NEt(2))(2)(thf)(3)](2+); the crystal structures of [U(NEt(2))(3)(thf)(3)] BPh(4) and [U(NEt(2))(2)(py)(5)] [BPh(4)](2) . 1.5py (py = pyridine) have been determined.

  DOI：

  10.1039/dt9950003019
• 作为产物：
  描述：

  [U(diethylamide)3]BPh₄ 在 tetrahydrofuran 作用下， 以 四氢呋喃 为溶剂， 生成 [U(diethylamide)3(tetrahydrofuran)3]BPh4
  参考文献：
  名称：

  Synthesis of cationic uranium compounds by protonolysis of amide precursors: amide and chloroamide complexes

  摘要：

  The chloroamide compounds [U(NEt(2))Cl-3(thf)] and [U(NEt(2))(2)Cl-2] were isolated from the comproportionation reactions of [U(NEt(2))(4)] and UCl4 in tetrahydrofuran (thf) and were converted respectively into the cationic derivatives [UCl3(thf)(2)]BPh(4) and [U(NEt(2))Cl-2(thf)(2)] BPh(4) by treatment with NHEt(3)BPh(4). Protonolysis of [U(NEt(2))(4)] afforded the monocation [U(NEt(2))(3)](+) which was itself transformed into the dication [U(NEt(2))(2)(thf)(3)](2+); the crystal structures of [U(NEt(2))(3)(thf)(3)] BPh(4) and [U(NEt(2))(2)(py)(5)] [BPh(4)](2) . 1.5py (py = pyridine) have been determined.

  DOI：

  10.1039/dt9950003019