([Cu(μ-hydrogen phthalate)(μ-azide)]*H2O)n | 187533-19-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ([Cu(μ-hydrogen phthalate)(μ-azide)]*H2O)n
• CAS: 187533-19-3
• 化学式: C₈H₅O₄*Cu*H₂O*N₃
• 分子量: 288.707
• InChiKey: RXVAMPIACSLFCM-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  sodium azide 、 copper(II) nitrate 、 邻苯二甲酸 以 乙醇 、 水 为溶剂， 生成 ([Cu(μ-hydrogen phthalate)(μ-azide)]*H2O)n
  参考文献：
  名称：

  Structure and Magnetic Behavior of a New 1-D Compound with Simultaneous End-On Azido and Carboxylato Bridges. Unexpected Strong Ferromagnetic Coupling for a Cu−N−Cu Bond Angle of 111.9° as a Consequence of Ligand HOMOs Countercomplementarity

  摘要：

  The X-ray structure of the mu-carboxylate-mu(1,1)-azido-bridged compound {[Cu(Hpht)(N-3)]. H2O}(n) has been determined (Hpht = hydrogen phthalate). Crystal data: formula C8H7CuN3O5, monoclinic, P2(1)/m (No. 11), a = 7.383(3) Angstrom, b = 6.568(4) Angstrom, c = 10.659(4) Angstrom, beta = 93.38(3)degrees, Z = 2. The compound is found to be a system formed by chains of copper atoms bridged simultaneously by syn-syn carboxylato and end-on azido bridges. The copper chains are linked by a second carboxylato bridge, giving a 2-D compound. Magnetic measurements indicate strong ferromagnetic coupling, which affords a good example of unexpected magnetic properties due to the countercomplementarity of the superexchange pathways of the two ligands.

  DOI：

  10.1021/ic961107j