copper(I) 2,6-bis(trifluoromethyl)benzoate | 943037-11-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: copper(I) 2,6-bis(trifluoromethyl)benzoate
• CAS: 943037-11-4
• 化学式: C₁₈H₆Cu₂F₁₂O₄
• 分子量: 641.316
• InChiKey: LOCUHBYYWLHUQC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,6-双(三氟甲基)苯甲酸 、 copper(I) trifluoroacetate 以 苯 为溶剂， 以62%的产率得到copper(I) 2,6-bis(trifluoromethyl)benzoate
  参考文献：
  名称：

  X-ray structure and photoluminescence of copper(I) 2,6-bis(trifluoromethyl)benzoate

  摘要：

  This report describes synthesis, X-ray crystallographic characterization, and photoluminescence of copper(I) 2,6-bis(trifluoromethyl)benzoate, [Cu(O2C(2,6-CF3)(2)C6H3)] (1). Complex 1 has a polymeric structure comprised of axially bound dinuclear [Cu-2(O2C(2,6-CF3)(2)C6H3)(2)] units that is reminiscent of the well-known structure of copper(I) acetate, [Cu-2(O2CMe)(2)] (2). However, a close comparison of two analogues revealed a non-planarity of 1D chains and their orthogonal disposition in the crystal structure of 1 versus parallel alignment of planar chains in 2. Complex 1 exhibits green photoluminescence at ca. 560 nin upon UV-radiation (lambda(ex) = 350 mn) in the solid state. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.02.023