Bis-{4-(pyridin-2-yl-methyleneamino)-3,5-dimethylphenyl}-methane | 500697-36-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis-{4-(pyridin-2-yl-methyleneamino)-3,5-dimethylphenyl}-methane
• 英文别名: N-[4-[[3,5-dimethyl-4-(pyridin-2-ylmethylideneamino)phenyl]methyl]-2,6-dimethylphenyl]-1-pyridin-2-ylmethanimine
• CAS: 500697-36-9
• 化学式: C₂₉H₂₈N₄
• 分子量: 432.568
• InChiKey: IUCAZZQWWIQROW-UHFFFAOYSA-N

物化性质

• 沸点：
  626.8±55.0 °C(Predicted)
• 密度：
  1.08±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  50.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Bis-{4-(pyridin-2-yl-methyleneamino)-3,5-dimethylphenyl}-methane 、 tetrakis(actonitrile)copper(I) hexafluorophosphate 以 甲醇 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Assembly of a Nanoscale Chiral Ball through Supramolecular Aggregation of Bowl-Shaped Triangular Helicates

  摘要：

  DOI：

  10.1002/1521-3773(20021115)41:22<4244::aid-anie4244>3.0.co;2-5
• 作为产物：
  描述：

  吡啶-2-甲醛 、 4-(4-氨基-3,5-二甲基苄基)-2,6-二甲基苯胺 在 甲酸 乙醇 作用下， 以 乙醇 为溶剂， 反应 16.0h， 以to afford 17 as a yellow solid (0.28 g, 18%)的产率得到Bis-{4-(pyridin-2-yl-methyleneamino)-3,5-dimethylphenyl}-methane
  参考文献：
  名称：

  Transition Metal Compounds for Olefin Polymerization and Oligomerization

  摘要：

  本发明涉及由公式（I）表示的新过渡金属催化剂化合物：其中：M和M'分别是8、9、10或11族过渡金属，优选为Ni、Co、Pd、Cu或Fe；每个R基团独立地是氢或烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基，并且选择性地，相邻的R基团可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；R'是氢或烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基，并且选择性地，相邻的R基团可以与R'结合在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；每个X基团独立地是氢、卤素或烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基，并且选择性地，相邻的X基团可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；m和m'独立地为0、1、2或3；z和z'独立地为0、1、2或3；N为氮；Q为氢或烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基；Q'为氢或烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基；以及L为烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基。

  公开号：

  US20080033125A1

文献信息

• [EN] SUPRAMOLECULAR COMPOUNDS AND THEIR USE AS ANTITUMOUR AND ANTIVIRAL AGENTS<br/>[FR] COMPOSES SUPRAMOLECULAIRES ET LEUR UTILISATION EN TANT QU'AGENTS ANTITUMORAUX ET ANTIVIRAUX
  申请人：UNIV WARWICK

  公开号：WO2005033119A1

  公开（公告）日：2005-04-14

  The application discloses the use of supramolecular compounds as antitumour, antimicrobial (such as antibacterial and antiprotozoal) and antiviral agents. Such compounds comprise ligands as defined in the application coordinated to at least two metal ions. Pharmaceutical formulations and detergent formulations are also disclosed.

  该申请披露了超分子化合物作为抗肿瘤、抗微生物（如抗菌和抗原虫）和抗病毒剂的用途。这些化合物包括在申请中定义的配体，配体与至少两个金属离子配位。此外还披露了药物配方和洗涤剂配方。
• Transition metal compounds for olefin polymerization and oligomerization
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US07741240B2

  公开（公告）日：2010-06-22

  This invention relates to new transition metal catalyst compounds represented by the formula (I): where: M and M′ are, independently, a group 8, 9, 10 or 11 transition metal, preferably Ni, Co, Pd, Cu or Fe; each R group is, independently, is, hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; R′ is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together with R′ to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; each X group is, independently, is, hydrogen, a halogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent X groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; m and m′ are, independently, 0, 1, 2, or 3; z and z′ are, independently, 0, 1, 2, or 3; N is nitrogen; Q is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents; Q′ is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents; and L is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent.

  本发明涉及一种新的过渡金属催化剂化合物，其表示为公式(I)：其中：M和M'分别是8、9、10或11族的过渡金属，优选为Ni、Co、Pd、Cu或Fe；每个R基团分别是氢、或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等，且相邻的R基团可以连接在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；R'是氢或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等，且相邻的R基团可以与R'连接在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；每个X基团分别是氢、卤素或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等，且相邻的X基团可以连接在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；m和m'分别为0、1、2或3；z和z'分别为0、1、2或3；N为氮；Q为氢或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等；Q'为氢或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等；L为碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等。
• Bridged bis-pyridinylimino dinickel(II) complexes: Syntheses, characterization, ethylene oligomerization and polymerization
  作者：Suyun Jie、Dongheng Zhang、Tianzhu Zhang、Wen-Hua Sun、Jiutong Chen、Qing Ren、Dongbing Liu、Gang Zheng、Wei Chen

  DOI：10.1016/j.jorganchem.2005.01.029

  日期：2005.3

  A series of bridged bis(pyridinylimino) ligands were efficiently synthesized through the condensation reaction of 4,4'-methylenebis(2,6-disubstituted aniline) with 2-pyridinecarboxaldehyde or 2-benzoylpyridine. They reacted with (DME)NiBr(2) to form dinuclear Ni(II) complexes. All resultant compounds were characterized by elemental analysis, IR spectra as well as the single-crystal X-ray diffraction to confirm the structures of ligands and complexes. Activated with methylaluminoxane (MAO), these nickel complexes showed considerably good activities for ethylene oligomerization and polymerization. Their catalytic activities and the properties of PEs obtained were depended on the arched environment of ligand and reaction conditions. (c) 2005 Elsevier B.V. All rights reserved.