aluminium chloride - triphenylphosphine | 14318-83-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: aluminium chloride - triphenylphosphine
• 英文别名: aluminum;triphenylphosphane;trichloride
• CAS: 14318-83-3
• 化学式: AlCl₃*C₁₈H₁₅P
• 分子量: 395.631
• InChiKey: BVGLYZYBTYYLEH-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -5.92
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  [Ph3PP.tplbond.NC6H2Bu(t)3-2,4,6][(C6H2(Bu(t)2-2,4,6)(Me)O)AlCl3] 以 氘代甲苯 为溶剂， 生成 aluminium chloride - triphenylphosphine 、 (2,6-Ditert-butyl-4-methylphenoxy)-(2,4,6-tritert-butylphenyl)iminophosphane
  参考文献：
  名称：

  Synthesis and characterization of new phosphanylium and phosphanetriylammonium salts. Molecular structures of [(Me₂N)PN(AlCl₃)R] and [P(NPrⁱ₂)(NHR)]⁺[CF₃SO₃]^–(R = C₆H₂Bu^t₃-2,4,6)

  摘要：

  The new internal salts [(R(1)R(2)N)PN(ECl(3))R] (E = Al or Ga; R = 2,4,6-Bu(3)(t)C(6)H(2)) and phosphanylium salts [P(NR(1)R(2))(NHR)](+)[C6(3)SO(3)](-) have been synthesized by treating aminoiminophosphanes (R(1)R(2)N)P=NR with AlCl3, GaCl3 or CF3SO3H. Protonation of RHN-P=NR with trifluoromethanesulfonic acid led to the first stable phosphanylium salt [P(NHR)(2)](+)[CF3SO3](-) with two primary amino groups. In contrast, the reaction of AlCl3 with the (aryloxy) iminophosphane (R'O) P=NR (R' = 4.Me-2,6-Bu(2)(t)C(6)H(2)) led to the new aryl(phosphanetriyl)ammonium complex [PNR](+)[(R'O)AlCl3](-). All compounds were characterized by multinuclear NMR spectroscopy. The crystal structures of [(Me(2)N)PN(AlCl3)R] and [P(NPr2i)(NHR)](+)[(CFSO3)-S-3](-) have been determined by single-crystal X-ray diffractometry.

  DOI：

  10.1039/dt9940002925

文献信息

• Grigor'ev, A. A.; Kondrat`ev, Yu. V.; Suvorov, A. V., Journal of general chemistry of the USSR, 1989, vol. 59, p. 2273 - 2275
  作者：Grigor'ev, A. A.、Kondrat`ev, Yu. V.、Suvorov, A. V.、Misharev, A. D.

  DOI：——

  日期：——