| 33749-46-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 33749-46-1
• 化学式: C₄₄H₃₇Cl₂N₂O₂P₂Re
• 分子量: 944.85
• InChiKey: SBLRAFFHWBAYOP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 1-甲基-1-苯肼 以 乙醇 为溶剂， 以70%的产率得到(Z)-amino((4-methoxybenzoyl)diazenyl)bis(triphenyl-l5-phosphaneyl)rhenium(VI) chloride
  参考文献：
  名称：

  The cleavage of the NN bond of N,N-disubstituted hydrazines on rhenium. The preparation, reactions and x-ray crystal structures of [ReCl2(NH3)(NNCOC6H4-4-R)(PPh3)2] (R = H, OMe, NO2), [ReCl3(NNPh2)(PPh3)2], [ReCl2(N)(NNPh2)(PPH3)] and [ReCl(N)(Me2CNNCOPh)(PPh3)2]

  摘要：

  Reaction of the N,O-chelated complexes [ReCl2(N2COC6H4-4-R)(PPh3)2] (R = H, Me, NO2) with N,N- and certain N-substituted hydrazines gave the ammine complexes [ReCl2(NH3)(NNCOC6H4-4-R)(PPh3)2] [R = H (1), R = Me (2), R = NO2 (3)]. The mechanism is believed to involve intermolecular homolytic cleavage of the N-N bond. The X-ray structure of 1 revealed a pseudo-octahedral geometry with trans-phosphines. The ammine ligand is cis to the benzoyldiazenido group and the ammine hydrogens are hydrogen-bonded to the carbonyl oxygen.Reaction of [ReOCl3(PPh3)2] with excess Ph2NNH2.HCl in ethanol gave both [ReCl3(NNPh2)(PPh3)2] (6) and [ReCl2(N)(NNPh2)(PPh3)] (7). In the presence of base the rhenium(VII) cation [ReCl2(NNPh2)2(PPh3)+ was formed. The geometry of 7 was shown by X-ray structural determination to be a distorted square-based pyramid, with the nitride in the apical position. Attempted derivatization of 7 led to N-N bond cleavage and the generation of nitrido complexes.The nitrido complex [ReCl(N)(Me2CNNCOPh)(PPh3)2] (8) was unexpectedly formed in the reaction of [ReOCl3(PPh3)2] with Me2C=NNHCOPh in ethanol in the presence of HCl. The X-ray crystal structure of 8 showed a pseudo-octahedral geometry with the nitride ligand trans to the oxygen of the N,O-chelated hydrazonato(1-) ligand. The possible mechanisms of N-N bond cleavage are discussed.

  DOI：

  10.1016/s0277-5387(00)83403-8