2-methylthiopyridinium perchlorate | 175235-37-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2-methylthiopyridinium perchlorate
• CAS: 175235-37-7
• 化学式: C₆H₇NS*ClHO₄
• 分子量: 225.653
• InChiKey: CBWAJTZUKNOZCA-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  gold (acetylacetonato) triphenylphosphane 、 2-methylthiopyridinium perchlorate 以 丙酮 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Complexes with S‐Donor Ligands, 4. Mono‐ and Di‐Homo‐ and ‐Hetero‐Nuclear Gold(I), Silver(I), and Palladium(II) Complexes with 2‐(Methylthio)pyridine, Pyridine‐2(1 H )‐thione, and Benzoxazole‐2(3 H )‐thione. Some Examples of the Use of Complexes as Ligands

  摘要：

  AbstractAgClO4 reacts with bidentate ligands 2‐(methylthio)pyridine (SMepy) or complexes PPN[Au(Spy)2] [PPN = N(PPh3)2, HSpy = pyridine‐2(1H)‐thione) or PPN[Au(Sbz)2] (HSbz = benzoxazole‐2(3H)‐thione), themselves acting as ligands, to give dinuclear complexes [Ag2(μ‐SMepy)2](ClO4)2 (1), [AgAu(μ‐Spy)2] (2), or [AgAu(μ‐Sbz)2] (3), respectively. By treating 1 with [AuCl(tht)] (tht = tetrahydrothiophene), [Au(SMepy)(tht)]ClO4 (4) is obtained which, in turn, reacts with SMepy to give [Au(SMepy)2]ClO4 (5). Similarly, [PdCl2(NCPh)2] reacts with SMepy in 1:1 molar ratio to give [Pd2Cl2(μ‐Cl)2(SMepy)2] (6) which reacts with SMepy in 1:2 molar ratio to give [PdCl2(SMepy)2] (7). On the other hand, HSpy reacts with Ag2CO3 to give [Ag2(μ‐Spy)2] (8), and (SMepyH)ClO4 reacts with [Au(acac)PPh3] (acacH = acetyl‐acetone) to give [Au(SMepy)PPh3]ClO4 (9).

  DOI：

  10.1002/cber.19961290313