1,1'-bis((diphenylphosphino)methyl)ferrocene | 160393-24-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1'-bis((diphenylphosphino)methyl)ferrocene
• 英文别名: .muu.-1,1'-bis(diphenylphosphinomethyl)ferrocene；cyclopenta-1,3-dien-1-ylmethyl(diphenyl)phosphane;iron(2+)
• CAS: 160393-24-8
• 化学式: C₃₆H₃₂FeP₂
• 分子量: 582.445
• InChiKey: ZUWUSYSSRHHJPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [RuCl2(hexamethylbenzene)]2 、 1,1'-bis((diphenylphosphino)methyl)ferrocene 以 二氯甲烷 为溶剂， 以67%的产率得到[(η(6)-hexamethylbenzene)RuCl2]2(μ-1,1'-bis[(diphenylphosphino)methyl]ferrocene-P,P')
  参考文献：
  名称：

  制剂和（的结构η 6 -arene）钌（II）配合物轴承1,1'-双（二苯基膦基）二茂铁或1,1'-双（二苯基膦基）二茂铁

  摘要：

  双反应[二氯（η 6 -arene）钌] 1用1,1'-双[（二苯基膦基）甲基]二茂铁（DPMF）得到dpmf- P，P'桥接的配合物[（η 6 -arene）的RuCl 2 ] 2（μ- dpmf）2，其中芳烃＝（a）1,2,3,4-Me 4 C 6 H 2；（b）C 6 Me 6 ; （c）对伞花烃；（d）1,2,3,5-Me 4 C 6 H 2；（e）1,3,5-Me 3 C 6 H 3；（f）1,2,3-Me 3 C 6 H 3。的治疗2与的NaPF存在二甲苯基胩（XylNC）6产生的F-配位的络合物[（η 6 -arene）的RuCl] 2（μ -dpmf）（PF 6）2图3a不含有XylNC。的反应1与形成在桥接配合物[（芳烃）的RuCl 1,1'-双（二苯基膦基）二茂铁（DPPF）2 ] 2（μ -dppf）] 4，以及dpmf复合体。在的NaPF的存在下，类似的反应6得到螯合配合物[（η

  DOI：

  10.1016/s0022-328x(98)00499-9
• 作为产物：
  描述：

  1,1'-bis(chloromethyl)ferrocene 、 二苯基膦酸锂 以 四氢呋喃 为溶剂， 以72%的产率得到1,1'-bis((diphenylphosphino)methyl)ferrocene
  参考文献：
  名称：

  Preparation of 1,1′-bis[(diphenylphosphino)methyl]ferrocene and its transition-metal complexes

  摘要：

  1,1'-Bis[(diphenylphosphino)methyl]ferrocene (dpmf), prepared from 1,1'-bis(chloromethyl)ferrocene and LiPPh2, reacted with [PdCl2(MeCN)2] to give [Pd2Cl2(dpmf2] 1, and treatment of 1 with [Pd3(2,6-Me2C6H3NC)6] in a 1 : 0.66 ratio in the presence of NH4PF6 and 2,6-Me2C6H3NC produced a macrocyclic complex [Pd4(2,6-Me2C6H3NC)8(dpmf)2]4+.

  DOI：

  10.1039/dt9940003191

文献信息

• Preparation and reactions of the (pentamethylcyclopentadienyl)rhodium(III) complexes bearing 1,1′-bis(diphenylphosphinomethyl)ferrocene (dpmf) or 1,1′-bis(diphenylphosphino)ferrocene (dppf)
  作者：Jian-Fang Ma、Yasuhiro Yamamoto

  DOI：10.1016/s0022-328x(98)00939-5

  日期：1999.2

  Reactions of [Cp*RhCl2]2 with 1,1′-bis(diphenylphosphinomethyl)ferrocene (dpmf) or 1,1′-bis(diphenylphosphino)ferrocene (dppf) gave the bridged complex [Cp*RnCl2]2(μ-diphos) (1: diphos=dpmf; 2: diphos=dppf). Reaction with dppf in the presence of NaPF6 gave the cationic chelated [Cp*RhCl(dppf-P,P′)](PF6) complex 3. Complex 1 reacted with xylyl isocyanide (XylNC) in the presence of NaPF6 to yield [C

  [Cp * RhCl 2 ] 2与1,1'-双（二苯基膦基甲基）二茂铁（dpmf）或1,1'-双（二苯基膦基）二茂铁（dppf）的反应得到桥联络合物[Cp * RnCl 2 ] 2（μ -diphos）（1：diphos = dpmf; 2：diphos = dppf）。在NaPF 6存在下与dppf反应，得到阳离子螯合的[Cp * RhCl（dppf- P，P '）]（PF 6）配合物3。在NaPF 6存在下，配合物1与二甲苯基异氰化物（XylNC）反应生成[Cp * 2 Rh 2 Cl 2（μ -dpmf）（XylNC）2 ]（PF 6）2，4，产量低。的[Cp *的Rh（dppf- P，P '）（MeCN中）]（PF 6）2，图5A，制备自3，的NaPF 6和硝酸银3在MeCN。在这种复杂的配位体的乙腈代替容易与路易斯碱（L），如CO和异氰化物，以形成的[Cp *的Rh（dppf- P，P
• Dimeric complexes of ruthenium(II) and rhodium(III) bridged by 1,1′-bis( diphenylphosphinomethyl) ferrocene
  作者：Jian-Fang Ma、Yasuhiro Yamamoto

  DOI：10.1016/s0022-328x(97)00415-4

  日期：1997.1

  Reactions of bis[dichloro(arene)ruthenium] or bis[dichloro(pentamethylcyclopentadicnyl)rhodium] with 1,1′-bis[(diphenylphosphino)methyl]ferrocene (dpmf) gave the dpmf-P,P′ bridged complexes. The reactions of the arene ruthenium complexes with 1,1′-bis[diphcnylphosphino]ferrocene (dppf) formed the bridged and chelated complexes. The structures of complexes were confirmed by X-ray analysis. The cyclic

  双[二氯（亚芳基）钌]或双[二氯（五甲基环戊二烯基）铑]与1,1'-双[（二苯基膦基）甲基]二茂铁（dpmf）的反应得到了dpmf- P，P '桥联的配合物。芳烃钌配合物与1，1'-双[二苯基膦基]二茂铁（dppf）的反应形成桥连和螯合的配合物。配合物的结构通过X射线分析确认。测量了钌配合物的循环伏安法。
• Reaction of di-μ-dichloro-bis(N,N-dimethylbenzylamine-C2,N)dipalladium(II) with diphosphines. Six-membered ring complexes bearing spiro rings
  作者：Jian-Fang Ma、Yasuhiro Yamamoto

  DOI：10.1016/s0020-1693(99)00491-0

  日期：2000.3

  Reactions of [Pd(C6H4CH2NMe2-C-2,N)(mu-Cl)](2) with diphosphines (diphos) such as dppf (a), dpmf (b), dppm (c), dppe (d) and dppp (e) gave [PdCl(C6H4CH2NMe2-C-2,N)](2)(mu-diphos) (2). Complexes 2 (a, b, d and e) reacted with NaPF6 to produce chelate complexes [Pd(C6H4CH2NMe2-C-2,N)(diphos-P,P')][PF6] (3), whereas 2c gave a six-membered ring complex [Pd-2(C6H4CH2NMe2-C-2,N)(2)(mu-Cl)(mu-dppm)][PF6] (4c) bearing two exocyclic rings shared by each palladium atom. This complex was regenerated to 2e by treatment with [NEt3(CH2Ph)]Cl. Treatment of 3 (a, d and e) with one equiv. of aq. HCl caused protonation at the coordinate nitrogen atom to yield [Pd(C6H4CH2NHMe2-C-2)(Cl)(diphos-P,P')][PF6] (5) (a, d and e). Reaction of 4e with aq. HCl in a 1:1 molar ratio led to protonation at one C-N chelating ring to give [Pd-2(Cl)(C6H4CH2-NMe2- C-2,N)(C6H4CH2NHMe2-C-2)(mu-Cl)(mu-dppm)][PF6] (6c). The structures of 2a, 3e, 4c, 5a and 6c were confirmed by X-ray analyses. (C) 2000 Elsevier Science S.A. All rights reserved.