| 202920-75-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 202920-75-0
• 化学式: C₃₂H₄₅P₄Rh
• 分子量: 656.51
• InChiKey: OYDCSSOXTBATPF-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  二甲基苯基磷 、 氯化铑(三水) 、 sodium tetrahydroborate 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Structures of HRh(PMe2Ph)4 and HRh(PPh2Me)4

  摘要：

  The mononuclear hydride complexes HRh(PMe2Ph)(4) (1) and HRh(PPh2Me)(4) (2) have been prepared and structurally analyzed by X-ray diffraction techniques. The geometry of both compounds consists of a distorted trigonal bipyramidal arrangement of ligands around rhodium. The hydride ligands were not located crystallographically, but were predicted by potential energy calculations to be situated at the axial positions. Crystallographic details: both compounds crystallize in the triclinic space group P (1) over bar. For HRh(PMe2Ph)(4) (1): a = 11.058(4), b = 16.332(4), c = 9.530(3) Angstrom, alpha = 94.07(2), beta = 99.37(3), gamma = 102.21(3)degrees, V = 1662.4(9) Angstrom(3) for Z = 2; R-F = 0.0463, R-wF = 0.0496 for 3550 reflections with I > 3 sigma(I). For HRh(PPh2Me)(4) (2): a = 13.061(6), b = 16.672(7), c = 12.150(6) Angstrom, alpha = 107.30(3), beta = 114.19(3), gamma = 71.45(4)degrees, V = 2245(2) Angstrom(3) for Z = 2; R-F = 0.0482, R-wF = 0.0488 for 4350 reflections with I > 3 sigma(I). (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05786-1