(2R,4S,6S)-2-(3,4-Dimethoxy-phenyl)-6-[(S)-1-hydroxy-2-(4-methoxy-phenyl)-ethyl]-tetrahydro-pyran-4-ol | 184478-53-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: (2R,4S,6S)-2-(3,4-Dimethoxy-phenyl)-6-[(S)-1-hydroxy-2-(4-methoxy-phenyl)-ethyl]-tetrahydro-pyran-4-ol
• CAS: 184478-53-3
• 化学式: C₂₂H₂₈O₆
• 分子量: 388.461
• InChiKey: IUKWBUHRPVDJSM-YRLHULLVSA-N

反应信息

• 作为反应物：
  描述：

  (R)-(+)-α-甲氧基-α-(三氟甲基)苯乙酸 、 (2R,4S,6S)-2-(3,4-Dimethoxy-phenyl)-6-[(S)-1-hydroxy-2-(4-methoxy-phenyl)-ethyl]-tetrahydro-pyran-4-ol 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以5 mg的产率得到(R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-[(2S,4S,6R)-6-(3,4-dimethoxy-phenyl)-4-((R)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-tetrahydro-pyran-2-yl]-2-(4-methoxy-phenyl)-ethyl ester
  参考文献：
  名称：

  Three diarylheptanoids from Rhoiptelea chiliantha

  摘要：

  Three new diarylheptanoids, rhoiptelols A, B and C, were isolated from the leaves and fruits of Rhoiptelea chiliantha. Their structures including absolute configurations were elucidated on the basis of spectral and chemical evidence. The chemotaxonomy of Rhoipteleaceae is also discussed. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0031-9422(96)00390-1
• 作为产物：
  描述：

  重氮甲烷 、 rhoiptelol B 以 甲醇 、 乙醚 为溶剂， 以19 mg的产率得到(2R,4S,6S)-2-(3,4-Dimethoxy-phenyl)-6-[(S)-1-hydroxy-2-(4-methoxy-phenyl)-ethyl]-tetrahydro-pyran-4-ol
  参考文献：
  名称：

  Three diarylheptanoids from Rhoiptelea chiliantha

  摘要：

  Three new diarylheptanoids, rhoiptelols A, B and C, were isolated from the leaves and fruits of Rhoiptelea chiliantha. Their structures including absolute configurations were elucidated on the basis of spectral and chemical evidence. The chemotaxonomy of Rhoipteleaceae is also discussed. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0031-9422(96)00390-1