piperazine-1,4-diylbis(methylene)bis(phosphinic acid) | 1080-17-7

• 分子结构分类: 有机化合物
• 英文名称: piperazine-1,4-diylbis(methylene)bis(phosphinic acid)
• 英文别名: Piperazinylen-(1,4)-bis-(methylphosphonigsaeure)；piperazine-1,4-diyldimethyl-bis-phosphinic acid
• CAS: 1080-17-7
• 化学式: C₆H₁₆N₂O₄P₂
• 分子量: 242.152
• InChiKey: NVFPUTGUFGEAFO-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  piperazine-1,4-diylbis(methylene)bis(phosphinic acid) 、 cobalt(II) perchlorate hexahydrate 以 水 为溶剂， 生成
  参考文献：
  名称：

  Syntheses and crystal structures of cobalt(II) complexes with piperazine-1,4-diylbis(methylene)bis(phosphinic) acid

  摘要：

  The synthesis of compounds of piperazine-1,4-diylbis(methylene)bis(phosphinic) acid (H(2)L) (1) with Co-II is described and the X-ray structures of the isolated complexes [Co(H(2)L)(3)](ClO4)(2) . 2H(2)O (2) and [Co(H2O)(6)]L (3), have been determined. Compound 2 forms a three-dimensional polymeric network of cobalt atoms bridged by 1, which is monodentately coordinated to cobalt through the phosphinate groups.:The nitrogen atoms are protonated and non-coordinated. In 3, 1 is deprotonated and forms non-coordinated anions and the octahedral coordination sphere of the cobalt atoms consists of water molecules.

  DOI：

  10.1016/0277-5387(95)00177-t