Hg(N-methyl-N-phenyldithiocarbamate)(N-ethyl-N-phenyldithiocarbamate) | 1269783-23-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Hg(N-methyl-N-phenyldithiocarbamate)(N-ethyl-N-phenyldithiocarbamate)
• CAS: 1269783-23-4
• 化学式: C₁₇H₁₈HgN₂S₄
• 分子量: 579.197
• InChiKey: KEOUTVIOLXUJRU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  24.0
• 可旋转键数：
  3.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  sodium N-ethyl-N-phenyldithiocarbamate 、 sodium N-methyl-N-phenyldithiocarbamate 、 mercury dichloride 以 水 为溶剂， 以72%的产率得到Hg(N-methyl-N-phenyldithiocarbamate)(N-ethyl-N-phenyldithiocarbamate)
  参考文献：
  名称：

  Synthesis of hexadecylamine capped nanoparticles using group 12 complexes of N-alkyl-N-phenyl dithiocarbamate as single-source precursors

  摘要：

  Metal complexes of the type (MLL2)-L-1 [M = Zn, Cd, Hg; L-1 = N-methyl-N-phenyldithiocarbamato and L-2 = N-ethyl-N-phenyldithiocarbamato] have been synthesized and characterized by elemental analyses, FT-IR and NMR spectroscopy. The complexes are formulated as four coordinate species with the dithiocarbamates acting as bidentate chelating ligands. The complexes were thermolysed and used as single-source precursors for the synthesis of HDA-capped MS (M = Zn, Cd, Hg) nanoparticles. The HgS nanoparticles show a narrow size distribution from their TEM images, while the CdS nanoparticles gave crystalline particles with a sharp band absorption edge and a narrow PL band. The ZnS nanoparticles gave crystalline particles with a stacking arrangement. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.10.023