Gd(TPyP)acac | 171295-16-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Gd(TPyP)acac
• CAS: 171295-16-2
• 化学式: C₄₅H₃₁GdN₈O₂
• 分子量: 873.044
• InChiKey: VQKPSHMAHNMTFO-NGRCPIEASA-N

反应信息

• 作为反应物：
  描述：

  Gd(TPyP)acac 、 碘甲烷 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Cationic lanthanide monoporphyrinates with Sm, Eu, Gd and Tb, synthesis and spectroscopic properties in aqueous and non-aqueous media

  摘要：

  The synthesis of a new series of cationic monoporphyrinates with ''light'' lanthanide ions is reported. The meso-tetrakis(4-pyridyl)porphyrin, (tpyp)H-2, was used as the tetrapyrrole ligand, and the metallation reaction with the lanthanide ions in acetyl-acetonato form, leading to Ln(tpyp)acac, where Ln = Sm, Eu, Gd and Tb, was carried out. The cationic monoporphyrinates, Ln(tmepyp)acac, were synthesized via the corresponding Ln(tpyp)acac. These complexes are freely soluble in aqueous and non-aqueous solutions, like MeOH, H2O or N,N-dimethylformamide. Their spectroscopic properties in water and DMF solutions are reported. All the complexes were characterized on the basis of their UV-vis, IR and ESR data. No ESR spectra were obtained for cationic porphyrins in DMF for Sm, Eu and Tb, while the spectra of Gd(tmepyp)acac in DMF exhibits smaller Delta H-pp (103.1 G) among the spectra of Gd-III complexes. The unexpected broad signal of Eu(t-mepyp)acac, Delta H-pp = 126.9 G, in H2O is discussed in terms of the formal oxidation state +2 for the central ion.

  DOI：

  10.1016/0277-5387(95)00175-r
• 作为产物：
  描述：

  5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine 、 gadolinium acetylacetonate hydrate 以 further solvent(s) 为溶剂， 以92%的产率得到Gd(TPyP)acac
  参考文献：
  名称：

  Cationic lanthanide monoporphyrinates with Sm, Eu, Gd and Tb, synthesis and spectroscopic properties in aqueous and non-aqueous media

  摘要：

  The synthesis of a new series of cationic monoporphyrinates with ''light'' lanthanide ions is reported. The meso-tetrakis(4-pyridyl)porphyrin, (tpyp)H-2, was used as the tetrapyrrole ligand, and the metallation reaction with the lanthanide ions in acetyl-acetonato form, leading to Ln(tpyp)acac, where Ln = Sm, Eu, Gd and Tb, was carried out. The cationic monoporphyrinates, Ln(tmepyp)acac, were synthesized via the corresponding Ln(tpyp)acac. These complexes are freely soluble in aqueous and non-aqueous solutions, like MeOH, H2O or N,N-dimethylformamide. Their spectroscopic properties in water and DMF solutions are reported. All the complexes were characterized on the basis of their UV-vis, IR and ESR data. No ESR spectra were obtained for cationic porphyrins in DMF for Sm, Eu and Tb, while the spectra of Gd(tmepyp)acac in DMF exhibits smaller Delta H-pp (103.1 G) among the spectra of Gd-III complexes. The unexpected broad signal of Eu(t-mepyp)acac, Delta H-pp = 126.9 G, in H2O is discussed in terms of the formal oxidation state +2 for the central ion.

  DOI：

  10.1016/0277-5387(95)00175-r

文献信息

• Synthesis, UV-visible and electrochemical studies of lipophilic and hydrophilic lanthanide(III) bis(porphyrinates)
  作者：G.A. Spyroulias、D. de Montauzon、A. Maisonat、R. Poilblanc、A.G. Coutsolelos

  DOI：10.1016/s0020-1693(97)06078-7

  日期：1998.7