{2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridinato}dioxoosmium(VI) | 142709-39-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridinato}dioxoosmium(VI)
• CAS: 142709-39-5
• 化学式: C₃₃H₂₇NO₄Os
• 分子量: 691.782
• InChiKey: MLSDLINMUKPOOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridinato}dioxoosmium(VI) 在 pyridine 作用下， 以 氯仿 为溶剂， 生成 {2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridinato}dioxo(pyridine)osmium(VI)
  参考文献：
  名称：

  Oxo-, nitrido- and imido-osmium(VI) complexes with a sterically bulky chelating alkoxide ligand

  摘要：

  The synthesis and characterization of dioxoosmium(VI) complexes cis-[OsO2L] and trans-[OsO2L'] (L' = NH2But, pyridine or 4-tert-butylpyridine), the nitrido complex [OsN(L)Cl], and imido complexes [OsL(NCOCF3)Cl(O2CCF3)] and [OsL(NPh)2] [H2L = 2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridine] are described. The crystal structures of [OsN(L)Cl] and [OsO2L(NH2But)].0.5C6H14 have been determined: the Os=N and average Os=O bond distances are 1.634(5) and 1.741(5) angstrom, respectively.

  DOI：

  10.1039/dt9920001657
• 作为产物：
  描述：

  potassium osmate 、 2,6-bis(2,2-diphenyl-2-hydroxyethyl)pyridine 以 甲醇 为溶剂， 生成 {2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridinato}dioxoosmium(VI)
  参考文献：
  名称：

  Oxo-, nitrido- and imido-osmium(VI) complexes with a sterically bulky chelating alkoxide ligand

  摘要：

  The synthesis and characterization of dioxoosmium(VI) complexes cis-[OsO2L] and trans-[OsO2L'] (L' = NH2But, pyridine or 4-tert-butylpyridine), the nitrido complex [OsN(L)Cl], and imido complexes [OsL(NCOCF3)Cl(O2CCF3)] and [OsL(NPh)2] [H2L = 2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridine] are described. The crystal structures of [OsN(L)Cl] and [OsO2L(NH2But)].0.5C6H14 have been determined: the Os=N and average Os=O bond distances are 1.634(5) and 1.741(5) angstrom, respectively.

  DOI：

  10.1039/dt9920001657