2-Diethylamino-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholane | 73000-27-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Diethylamino-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholane
• 英文别名: N,N-diethyl-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholidin-2-amine
• CAS: 73000-27-8
• 化学式: C₁₄H₂₃N₂OP
• 分子量: 266.323
• InChiKey: WZKFSLGSXJPWHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  15.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 2-Diethylamino-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholane 以 氯仿 为溶剂， 以91.7%的产率得到dichloroplatinum;N,N-diethyl-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholidin-2-amine
  参考文献：
  名称：

  Reactions of chiral phosphoramidites with complexes Pd(COD)Cl2 and Pt(COD)Cl2

  摘要：

  Reactions of phosphoramidites based on (-)-ephedrine and [(1S)-endo]-(-)-borneol with the complexes M(COD)Cl-2 (M is Pd or Pt, and COD is cycloocta-1,5-diene) were studied. The formation of cis and trans complexes of the general formulas MCl2L2 and M2Cl2(mu-Cl)(2)-L-2 was observed. The structures of the resulting compounds were established by P-31, C-13, and Pt-195 NMR and IR spectroscopy and by plasma desorption mass spectrometry.

  DOI：

  10.1007/bf02495615