1-[1,1,1,4,4,5,5,5-Octafluoro-2-(trifluoromethyl)pent-2-en-3-yl]azepane | 89810-73-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环庚烷
• 英文名称: 1-[1,1,1,4,4,5,5,5-Octafluoro-2-(trifluoromethyl)pent-2-en-3-yl]azepane
• CAS: 89810-73-1
• 化学式: C₁₂H₁₂F₁₁N
• 分子量: 379.216
• InChiKey: WNKAPLIKMMBOSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1-[1,1,1,4,4,5,5,5-Octafluoro-2-(trifluoromethyl)pent-2-en-3-yl]azepane 在 盐酸 作用下， 反应 20.0h， 以70%的产率得到2-(Trifluoromethyl)-1,1,1,4,4,5,5,5-octafluoropentan-3-one
  参考文献：
  名称：

  Reaction of secondary amines with hexafluoropropylene dimers

  摘要：

  DOI：

  10.1007/bf00954714
• 作为产物：
  描述：

  N,N-diperfluorodiethyl-N-(2-hydroperfluoro-2-methylpentyl)amine 在 三乙胺 作用下， 以 乙醚 为溶剂， 反应 17.0h， 生成 1-[1,1,1,4,4,5,5,5-Octafluoro-2-(trifluoromethyl)pent-2-en-3-yl]azepane
  参考文献：
  名称：

  Reaction of secondary amines with hexafluoropropylene dimers

  摘要：

  DOI：

  10.1007/bf00954714

文献信息

• SNEGIREV, V. F.;ZAXAROVA, E. V.;MAKAROV, K. N.;KNUNYANTS, I. L., IZV. AN CCCP. CEP. XIM., 1983, N 11, 2561-2568
  作者：SNEGIREV, V. F.、ZAXAROVA, E. V.、MAKAROV, K. N.、KNUNYANTS, I. L.

  DOI：——

  日期：——
• PERFLUOROAMINOOLEFINS AND METHODS OF MAKING AND USING THE SAME
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20210221776A1

  公开（公告）日：2021-07-22

  Described herein is a perfluorinated aminoolefin compound of general formula (I): CFY═CXN(R f )CF 2 R f ′ where: (a) R f and R f ′ are (i) independently selected from a linear or branched perfluoroalkyl group having 1-8 carbon atoms, optionally comprising at least one catenated O or N atom, or (ii) bonded together to form a perfluorinated ring structure having 4-8 ring carbon atoms, optionally comprising at least one catenated O atom; and (b) X and Y are (i) independently selected from a perfluoroalkyl group having 1-4 carbon atoms, or (ii) bonded together to form a perfluorinated ring structure having 5-6 ring carbon atoms. Such compounds may be used in heat transfer, foam blowing or immersion cooling applications, or as a working fluid in a Rankine cycle, a coating or lubricant, or as a dielectric fluid. Also disclosed herein is a method for making such compounds.