Ga(acac)3 、 tetramethyl ammonium hydroxide 、 以
not given 为溶剂,
生成
参考文献:
名称:
Stereospecificity and Self-Selectivity in the Generation of a Chiral Molecular Tetrahedron by Metal-Assisted Self-Assembly
摘要:
The chiral bidentate ligand (S,S)-1 reacts stereospecifically with Ga3+ to generate a [Ga4 (L)6 ]12- molecular tetrahedron although similar ligands generate [Ga2 (L)3 ]6- complexes. The assembly of this complex is self-selective as a racemic mixture of the ligand sorts by chirality to generate an enantiomeric pair of homochiral complexes.