phenyl di(hex-5-en-1-yl) phosphate | 1403661-65-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl di(hex-5-en-1-yl) phosphate
• 英文别名: Bis(hex-5-enyl) phenyl phosphate
• CAS: 1403661-65-3
• 化学式: C₁₈H₂₇O₄P
• 分子量: 338.384
• InChiKey: BXURFGUNHUDMHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  23
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  5-己烯-1-醇 、 二氯磷酸苯酯 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 以75%的产率得到phenyl di(hex-5-en-1-yl) phosphate
  参考文献：
  名称：

  Unsaturated Polyphosphoesters via Acyclic Diene Metathesis Polymerization

  摘要：

  A powerful methodology for the synthesis of unsaturated polyphosphoesters (UPPEs) relying on acyclic diene metathesis (ADMET) polymerization is described. A facile two-step protocol gives fast access to structurally versatile and potentially degradable and biocompatible materials. For the first time this allows to control the microstructure of either backbone and/or side chains of polyphosphoesters. Four different, monomers are polymerized under different conditions to yield UPPEs with molecular weights ranging from 7000 up to 50 000 g.mol(-1) with reasonable polydispersity. The unsaturated and saturated polyphosphoesters are characterized in detail with various techniques. A major benefit of the UPPEs is revealed by differential scanning calorimetry proving the control over thermal properties with tunable melting or glass transition temperatures for the different saturated and unsaturated PPEs which is an important feature for future applications. This unique combination of the benefits of metathesis polymerization and phosphorus chemistry is a highly versatile system for materials in many applications ranging from adhesives to biomaterials.

  DOI：

  10.1021/ma301508s

文献信息

• Long-term stable photoactive composition, such as phosphorescent composition or TTA-photon upconversion composition
  申请人：Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

  公开号：EP2851407A1

  公开（公告）日：2015-03-25

  A long-term stable photoactive composition, such as a phosphorescent composition or a TTA-photon upconversion composition, contains at least one compound, which has a triplet state capable of energy transfer via an emissive process or a non-emissive process, and at least one compound capable of reacting with singlet oxygen, wherein the at least one compound capable of reacting with singlet oxygen comprises at least one terminal unsaturated carbon-carbon bond, and wherein the at least one compound capable of reacting with singlet oxygen is contained in the composition in such an amount that the number of terminal unsaturated carbon-carbon bonds is at least 100 times higher in the composition than the number of molecules of all compounds having a triplet state capable of energy transfer via an emissive process or a non-emissive process.

  一种长期稳定的光活性组合物，如磷光组合物或 TTA 光子上转换组合物，包含至少一种化合物，该化合物具有能够通过发射过程或非发射过程进行能量转移的三重态，以及至少一种能够与单线态氧反应的化合物，其中至少一种能够与单线态氧反应的化合物包含至少一个末端不饱和碳-碳键、其中至少一种能与单线态氧反应的化合物在组合物中的含量，使组合物中末端不饱和碳-碳键的数量比所有具有能通过发射过程或非发射过程进行能量转移的三重态的化合物分子数量至少高 100 倍。
• CAPSULE SUITABLE FOR NON-INVASIVE SIMULTANEOUS OXYGEN CONTENT AND TEMPERATURE SENSING IN A LIVING OBJECT
  申请人：Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

  公开号：EP3072942A1

  公开（公告）日：2016-09-28

  A capsule suitable for oxygen and temperature sensing contains: i) at least one first sensitizer compound being capable of energy transfer to triplet oxygen, ii) at least one compound being capable of reacting with and inactivating singlet oxygen, iii) at least one second sensitizer compound being capable of absorbing radiation at a second frequency v2 and of emitting light at a fourth frequency v4, iv) at least one emitter compound, wherein the at least one second sensitizer compound is capable of transferring energy to the at least one emitter compound and wherein the at least one emitter compound, after obtaining energy transferred from the at least one second sensitizer compound, is capable of emitting light at a third frequency v3, wherein the following equation is fulfilled: v3>v2, wherein the upper energy limit of the first triplet energy band of the first sensitizer compound is lower than the lower energy limit of the second triplet energy band of the second sensitizer compound and lower than the lower energy limit of the third triplet energy band of the emitter compound, and wherein the third triplet band of the emitter compound at least partially overlaps with the second triplet energy band of the second sensitizer compound.

  适用于氧气和温度传感的胶囊包含 i) 至少一种能与三重态氧发生能量转移的第一敏化剂化合物、 至少一种能与单线态氧反应并使其失活的化合物、 iii) 至少一种第二敏化剂化合物能够以第二频率 v2 吸收辐射，并以第四频率 v4 发射光、 iv) 至少一种发射器化合物，其中至少一种第二敏化剂化合物能够将能量传递给至少一种发射器化合物，其中至少一种发射器化合物在获得至少一种第二敏化剂化合物传递的能量后，能够以第三频率 v3 发射光，其中满足以下等式：v3>v2、 其中，第一敏化剂化合物的第一三重能带的能量上限低于第二敏化剂化合物的第二三重能带的能量下限，且低于发射器化合物的第三三重能带的能量下限，发射器化合物的第三三重能带至少与第二敏化剂化合物的第二三重能带部分重叠。
• Capsule suitable for non-invasive simultaneous oxygen content and temperature sensing in a living object
  申请人：MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V.

  公开号：US10739334B2

  公开（公告）日：2020-08-11

  A capsule suitable for oxygen and temperature sensing contains: i) at least one first sensitizer compound being capable of energy transfer to triplet oxygen, ii) at least one compound being capable of reacting with and inactivating singlet oxygen, iii) at least one second sensitizer compound being capable of absorbing radiation at a second frequency v2 and of emitting light at a fourth frequency v4, iv) at least one emitter compound, wherein the at least one second sensitizer compound is capable of transferring energy to the at least one emitter compound and wherein the at least one emitter compound, after obtaining energy transferred from the at least one second sensitizer compound, is capable of emitting light at a third frequency v3, wherein the following equation is fulfilled: v3>v2, wherein the upper energy limit of the first triplet energy band of the first sensitizer compound is lower than the lower energy limit of the second triplet energy band of the second sensitizer compound and lower than the lower energy limit of the third triplet energy band of the emitter compound, and wherein the third triplet band of the emitter compound at least partially overlaps with the second triplet energy band of the second sensitizer compound.

  适用于氧气和温度传感的胶囊包括 i) 至少一种能与三重态氧发生能量转移的第一敏化剂化合物、 至少一种能与单线态氧反应并使其失活的化合物、 iii) 至少一种第二敏化剂化合物能够以第二频率 v2 吸收辐射，并以第四频率 v4 发射光、 iv) 至少一种发射器化合物，其中至少一种第二敏化剂化合物能够将能量传递给至少一种发射器化合物，其中至少一种发射器化合物在获得至少一种第二敏化剂化合物传递的能量后，能够以第三频率 v3 发射光，其中满足以下等式：v3>v2、 其中，第一敏化剂化合物的第一三重能带的能量上限低于第二敏化剂化合物的第二三重能带的能量下限，且低于发射器化合物的第三三重能带的能量下限，发射器化合物的第三三重能带至少与第二敏化剂化合物的第二三重能带部分重叠。
• LONG-TERM STABLE PHOTOACTIVE COMPOSITION, SUCH AS PHOSPHORESCENT COMPOSITION OR TTA-PHOTON UPCONVERSION COMPOSITION
  申请人：Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

  公开号：EP3049502B1

  公开（公告）日：2020-04-01
• [EN] CAPSULE SUITABLE FOR NON-INVASIVE SIMULTANEOUS OXYGEN CONTENT AND TEMPERATURE SENSING IN A LIVING OBJECT<br/>[FR] CAPSULE APPROPRIÉE POUR LA DÉTECTION NON EFFRACTIVE SIMULTANÉE DE LA TENEUR EN OXYGÈNE ET LA TEMPÉRATURE CHEZ UN SUJET VIVANT
  申请人：MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WSS E V

  公开号：WO2016150677A1

  公开（公告）日：2016-09-29

  A capsule suitable for oxygen and temperature sensing contains: i) at least one first sensitizer compound being capable of energy transfer to triplet oxygen, ii) at least one compound being capable of reacting with and inactivating singlet oxygen, iii) at least one second sensitizer compound being capable of absorbing radiation at a second frequency v2 and of emitting light at a fourth frequency v4, iv) at least one emitter compound, wherein the at least one second sensitizer compound is capable of transferring energy to the at least one emitter compound and wherein the at least one emitter compound, after obtaining energy transferred from the at least one second sensitizer compound, is capable of emitting light at a third frequency v3, wherein the following equation is fulfilled: v3>v2, wherein the upper energy limit of the first triplet energy band of the first sensitizer compound is lower than the lower energy limit of the second triplet energy band of the second sensitizer compound and lower than the lower energy limit of the third triplet energy band of the emitter compound, and wherein the third triplet band of the emitter compound at least partially overlaps with the second triplet energy band of the second sensitizer compound.