1-methyl-8-amino-3-thia-6,10,13,16,19-pentaazabicyclo[6.6.6]icosane | 148716-33-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 有机二硫化物
• 英文名称: 1-methyl-8-amino-3-thia-6,10,13,16,19-pentaazabicyclo[6.6.6]icosane
• CAS: 148716-33-0
• 化学式: C₁₅H₃₄N₆S
• 分子量: 330.541
• InChiKey: OZWWTMGEUNCHTE-GASCZTMLSA-N

反应信息

• 作为反应物：
  描述：

  1-methyl-8-amino-3-thia-6,10,13,16,19-pentaazabicyclo[6.6.6]icosane 、 lithium perchlorate 、 nickel(II) perchlorate 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Stranger, Robert; McMahon, Katie L.; Gahan, Lawrence R., Inorganic Chemistry, 1997, vol. 36, # 16, p. 3466 - 3475

  摘要：

  DOI：

文献信息

• Zinc(II) complexes of the encapsulating ligands 1-methyl-8-amino-3,13-dithia-6,10,16,19-tetraazabicyclo[6.6.6]icosane (AMN4S2sar) and 1-methyl-8-amino-3-thia-6,10,13,16,19-pentaazabicyclo[6.6.6]icosane (AMN5Ssar). X-ray structural characterization
  作者：James I. Bruce、Therese M. Donlevy、Lawrence R. Gahan、Colin H.L. Kennard、Karl A. Byriel

  DOI：10.1016/0277-5387(95)00221-d

  日期：1996.1

  The crystal structures of [Zn(AMN(4)S(2)sarH)](ClO4)(NO3)(2) . 2H(2)O(AMN(4)S(2)sar = 1-methyl-8-amino-3,13-dithia-6,10,16,19-tetraazabicyclo[6.6.6]icosane) and [Zn(AMN(5)Ssar)] (ClO4)(2) . 2H(2)O (AMN(5)Ssar = 1-methyl-8-amino-3-thia-6,10,13,16,19-pentazabicyclo[6.6.6] icosane) have been determined by X-ray diffraction methods. In each case the ligands effectively encapsulate the metal ion within a macrobicyclic cavity, a distorted octahedral environment resulting from both the-unsymmetrical nature of the mixed nitrogen and thioether donor atoms and the small size of the zinc(II) ion.