| 187171-76-2

• CAS: 187171-76-2
• 化学式: C₈H₁₂MoO₄P₂S₂
• 分子量: 394.2
• InChiKey: YLWUIMVOAIVNOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) 、 四甲基二膦烷二硫化物 以 正己烷 、 二氯甲烷 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Photochemical and thermal synthesis of metal carbonyl complexes of tetraalkyl diphosphine disulfides [M(CO)4(R2P(S)P(S)R2)] (M  Mo, W; R  Me, Et, Pr-n, Bu-n)

  摘要：

  The new complexes [M(CO)(4)(R(2)P(S)P(S)R(2))], 1A-1D, 2A-2D, (1A,M = Mo, R = Me; 1B, M = Mo, R = Et; 1C, M = Mo, R = Pr-n; 1D, M = Mo, R = Bu-n; 2A, M = W, R = Me; 2B; M = W, R = Et; 2C, M = W, R = Pr-n; 2D, M = W, R = Bu-n) have been prepared either by the photochemical reaction of M(CO)(6) with R(2)P(S)P(S)R(2), or by thermal displacement of coordinated norbornadiene in C7H8Mo(CO)(4) with R(2)P(S)P(S)R(2), to give the complexes [M(CO)(4)(R(2)P(S)P(S)R(2))]. The complexes have been characterized by elemental analysis, IR and P-31-[H-1]-NMR spectroscopy and FAB-Mass spectrometry; the spectroscopic studies suggest a cis-chelate bidentate coordination of the ligand. Copyright (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00384-1

文献信息

• PHOTOCHEMICAL SYNTHESIS OF METAL CARBONYL COMPLEXES OF TETRAALKYLDIPHOSPHINE DISULFIDES, [M₂(CO)₁₀(μ-R₂P(S)P(S)R₂)] (M = Mo, W; R = Me, Et,<i>n</i>-Pr,<i>n</i>-Bu)
  作者：Ozan Sanlı Şentürk、Fadime Ugˇur

  DOI：10.1081/sim-100108266

  日期：2001.11.30

  The new complexes [M-2(CO)(10)(mu-R2P(S)P(S)R-2)] (M = Mo, W: R = Me, Et, n-Pr, n-Bu), (1a)-(1d) and (2a)-(2d) [(1a), M = Mo, R = Me, (1b). M = Mo, R = Et; (1c), M = Mo, R = n-Pr, (1d), M = Mo, R = n-Bu. (2a), M = W, R = Me, (2b), M = W, R = Et, (2c), M = W, R n-Pr, (2d). M = W, R = n-Bu] have been prepared by the photochemical reaction of M(CO)(6) with R2P(S)P(S)R-2 (R = Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and P-31-[H-1]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.