(N,N'-bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine)dicyanooxomolybdenum(IV) monohydrate | 169622-36-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并吡啶类
• 英文名称: (N,N'-bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine)dicyanooxomolybdenum(IV) monohydrate
• CAS: 169622-36-0
• 化学式: C₁₈H₁₈MoN₆O*H₂O
• 分子量: 448.336
• InChiKey: UHQAKZXCUZJQER-BAPRHOIXSA-N

反应信息

• 作为产物：
  描述：

  2-乙酰基吡啶 、 K₃Na[Mo(CN)₄O₂]*6H₂O 在 1,2-diaminoethane 、 HCl 作用下， 以 水 、 丙酮 为溶剂， 以20%的产率得到(N,N'-bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine)dicyanooxomolybdenum(IV) monohydrate
  参考文献：
  名称：

  Structural and spectroscopic characterization of a dicyanooxomolybdenum(IV) complex with a tetradentate schiff-base ligand

  摘要：

  The reaction of protonated tetracyanodioxomolybdate(IV) ion with 2-acetylpyridine and ethane-1,2-diamine gave a new complex of formula [MoO(CN)(2)(L-L-L-L)]. H2P, where L-L-L-L = N,N'-bis[1-(pyridin-2-yl)ethylidene]ethane-1 ,2-diamine. The structure of this salt was determined by, X-ray analysis. Principal dimensions (ranges or means; estimated standard deviation +/-0.006 Angstrom) are Mo=O 1.689, Mo-C 2.157 and 2.168, Mo-N 2.273-2.329 Angstrom. The crystals are monoclinic, space group C2/c, a = 31.789(2), b = 8.194(1), c = 15.198(1) Angstrom, beta = 104.08(1)degrees, Z = 8; R = 0.032 for 4249 observed [F/sigma(F) > 4] reflections. The molybdenum is seven-co-ordinated with the L-L-L-L ligand and oxygen in one plane and cyanide ligands above and below this plane. The structure contains water molecules which form a network of hydrogen bonds with cyanide ligands. The IR and ESR spectra, as well as the results of ion-exchange and electrophoresis experiments, are in agreement with this structure. The visible spectra in various solvents are dominated by metal-to-ligand charge-transfer bands with absorption maxima linearly dependent on the Reichardt E(T) parameter. The complex undergoes one step, two-electron, reversible-oxidation with E(1/2) = 0.77 V.

  DOI：

  10.1039/dt9950003057