(E)-8-phenyl-7-octenal | 136066-75-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-8-phenyl-7-octenal
• 英文别名: (E)-8-phenyloct-7-enal
• CAS: 136066-75-6
• 化学式: C₁₄H₁₈O
• 分子量: 202.296
• InChiKey: NSFUOVANYCRVJT-UXBLZVDNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (E)-8-phenyl-7-octenal 、 5-amino-3-phenyl-thiazolidine-2,4-dione 生成 3-phenyl-5-[(E)-[(E)-8-phenyloct-7-enylidene]amino]-1,3-thiazolidine-2,4-dione
  参考文献：
  名称：

  RAO, T. N.;ASTIK, R. R.;THAKER, K. A., J. INST. CHEM., INDIA, 1982, 54, N 5, 211-212

  摘要：

  DOI：
• 作为产物：
  描述：

  (E,Z)-8-phenyl-7-octen-1-ol 在 草酰氯 、 二甲基亚砜 、 三乙胺 作用下， 生成 (E)-8-phenyl-7-octenal 、 (Z)-8-phenyl-7-octenal
  参考文献：
  名称：

  Intramolecular anodic olefin coupling reactions: a useful method for carbon-carbon bond formation

  摘要：

  The utility of intramolecular anodic olefin coupling reactions for effecting carbon-carbon bond formation has been examined. All of the successful cyclizations studied utilized either an alkyl or silyl enol ether as one of the participating olefins. The enol ethers could be coupled to simple alkyl olefins, styrenes, and allylsilanes in isolated yields ranging from 57 to 84%. The reactions were found to be effective for generating both five- and six-membered rings. The best conditions for cyclization utilized a reticulated vitreous carbon anode, constant-current conditions in an undivided cell, and a lithium perchlorate in either 50% methanol/tetrahydrofuran or 20% methanol/dichloromethane electrolyte solution. The use of an allylsilane as one of the participating olefins allowed for the regiospecific formation of olefinic products. In addition to the olefinic products, these reactions produced a small amount of a cyclized ether product in which the silyl group had not been eliminated. Deuterium-labeling studies showed that at least half of this ether byproduct arose from intramolecular migration of the methoxy group that was initially part of the starting enol ether to the carbon-beta to the silyl group. Intramolecular migration reactions of this type were found to participate in a number of the reported cyclization reactions.

  DOI：

  10.1021/ja00019a038

文献信息

• METAL MATERIAL WITH A BISMUTH FILM ATTACHED AND METHOD FOR PRODUCING SAME, SURFACE TREATMENT LIQUID USED IN SAID METHOD, AND CATIONIC ELECTRODEPOSITION COATED METAL MATERIAL AND METHOD FOR PRODUCING SAME
  申请人：NIHON PARKERIZING CO., LTD.

  公开号：EP2280096A1

  公开（公告）日：2011-02-02

  This invention provides a metal material with a bismuth coating being enables the subsequent coating to be accomplished at a high throwing power, and has excellent corrosion resistance, coating adhesion, and, being able to be produced with reduced damage to the environment, the metal material having a surface and a bismuth-containing layer deposited on at least a part of the surface of the metal material, wherein a percentage of bismuth atoms in number of atoms in the surface layer of the metal material with a bismuth coating is at least 10%.

  本发明提供了一种具有铋涂层的金属材料，该金属材料可在高投掷力下完成后续涂层，并具有优异的耐腐蚀性和涂层附着力，而且能够在生产过程中减少对环境的破坏，该金属材料具有一个表面和一个至少沉积在金属材料部分表面上的含铋层，其中铋原子在具有铋涂层的金属材料表面层的原子数中所占百分比至少为 10%。
• RAO, T. N.;ASTIK, R. R.;THAKER, K. A., J. INST. CHEM. (INDIA), 1981, 53, N 4, 174-176
  作者：RAO, T. N.、ASTIK, R. R.、THAKER, K. A.

  DOI：——

  日期：——
• MICROCAPSULES
  申请人：Givaudan S.A.

  公开号：EP3316972A1

  公开（公告）日：2018-05-09
• MÉLANGE COMPRENANT AU MOINS DE LA DIHYDRO-5-PENTYL-2(3H)-FURANONE ET DU 2,4-DIMÉTHYL-4-PHÉNYLTÉTRAHYDROFURANE ET SON UTILISATION POUR MASQUER LES MAUVAISES ODEURS
  申请人：Expressions Parfumees

  公开号：EP3471691A1

  公开（公告）日：2019-04-24
• PROCESS FOR INCORPORATING ANTIMICROBIAL PRODUCTS INTO SOAP COMPOSITIONS
  申请人：Renner Gerd-Friedrich

  公开号：US20110028545A1

  公开（公告）日：2011-02-03

  The present invention relates to a process for producing concentrates of antimicrobial active ingredients, the concentrates themselves and their use for producing solid, liquid or pasty body cleaning compositions, such as in particular soaps.