1,10-dithiocyanatodecane | 100526-39-4

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: 1,10-dithiocyanatodecane
• 英文别名: 1,10-bis-thiocyanato-decane；2,13-Dithia-tetradecandinitril；1,10-Bis-thiocyanato-decan；1,10-Dithiocyanato-decan；10-Thiocyanatodecyl thiocyanate
• CAS: 100526-39-4
• 化学式: C₁₂H₂₀N₂S₂
• 分子量: 256.436
• InChiKey: RKGGSCMFMXHLCI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  98.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,10-dithiocyanatodecane 在 水 、 氯 作用下， 生成 Decane 1,10-bis(sulfonyl)chloride
  参考文献：
  名称：

  Geiseler; Asinger, Chemische Berichte, 1956, vol. 89, p. 1100,1109

  摘要：

  DOI：
• 作为产物：
  描述：

  potassium thioacyanate 、 1,10-二溴癸烷 以 乙醇 为溶剂， 反应 2.0h， 生成 1,10-dithiocyanatodecane
  参考文献：
  名称：

  A new synthesis of trifluoromethyl sulfides utilizing thiocyanates and fluoroform

  摘要：

  Fluoroform is a potent greenhouse gas which should not be released to the atmosphere. Large amounts of it are stored and wait for new and useful reactions to be based on it. One such general reaction that is described in this paper is its use in preparation of the important organic trifluoromethyl sulfides. Aliphatic, aromatic and heterocyclic thiocyanates are easy to prepare. They were reacted with fluoroform-based CuCF3 to form the corresponding (trifluoromethyl)thio derivatives. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2014.09.026

文献信息

• Vulcanisable rubber composition and compounds useful as stabilising agents for rubber vulcanisates
  申请人：MONSANTO EUROPE S.A.

  公开号：EP0129527A2

  公开（公告）日：1984-12-27

  Additives tor rubber compositions, giving vulcanisates having improved retention of optimum physical properties, are compounds having the formula R-S-B-S-R where B is an organic bridging group and R is an electron-withdrawing group, for example CN, CCl3, a radical containing an activated methylene group linked to the sulphur atom or the enolic tautomer of a keto-activated methylene group. Also useful as stabilising agents are oligomeric analogues of such compounds.

  具有 R-S-B-S-R 式的化合物是橡胶组合物的添加剂，可使硫化胶更好地保持最佳物理性能，其中 B 是有机桥基，R 是抽电子基团，例如 CN、CCl3、含有与硫原子相连的活化亚甲基的自由基或酮活化亚甲基的烯醇同系物。 这类化合物的低聚类似物也可用作稳定剂。
• Dithiocyanates useful as stabilising agents for rubber vulcanisates
  申请人：MONSANTO EUROPE S.A.

  公开号：EP0306823A1

  公开（公告）日：1989-03-15

  Dithiocyanates having the formula NCS-B-SCN where B is an organic bridging group are useful for stabilising the properties of rubber vulcanisates, for example by improving reversion resistance.

  式中的二硫氰酸盐 NCS-B-SCN 其中 B 为有机桥基，可用于稳定橡胶硫化胶的性能，例如提高抗还原性。
• APPARATUS AND METHOD FOR PRODUCING RESIN
  申请人：TEIJIN LIMITED

  公开号：EP1120435A1

  公开（公告）日：2001-08-01

  A method of producing a polycarbonate or the like which is excellent in hydrolysis and heat stability such as a reduction in molecular weight at the time of molding and color retention and moldability such as releasability and transferability, rarely experiences residence deterioration such as coloring, crosslinking and gel formation and has an extremely small content of foreign matter by employing a special structure for an opening in the side surface of a horizontal cylindrical vacuum resin treating apparatus, supplying a molten polycarbonate into a unidirectional rotary intermeshing double-screw extruder under specific conditions, adding a specific agent under specific conditions and cleaning the inner surface of a production apparatus by a specific method.

  一种聚碳酸酯或类似物的生产方法，该聚碳酸酯或类似物具有优异的水解稳定性和热稳定性（如成型时分子量降低）以及保色性和成型性（如脱模性和转移性），很少发生着色等居住劣化、通过在卧式圆柱形真空树脂处理装置的侧表面开口处采用特殊结构，在特定条件下将熔融聚碳酸酯送入单向旋转啮合双螺杆挤出机，在特定条件下添加特定药剂，并通过特定方法清洁生产装置的内表面，可生产出异物含量极低的聚碳酸酯。
• POLYCARBONATE, PROCESS FOR PRODUCING THE SAME, AND MOLDED ARTICLE THEREOF
  申请人：TEIJIN LIMITED

  公开号：EP1191049A1

  公开（公告）日：2002-03-27

  A polycarbonate which is stable against thermal decomposition at a temperature range for melt molding without adding a heat resistant stabilizer and suitable for the melt molding of a thin product, production method and molded products thereof. The polycarbonate is comprising mainly a recurring unit represented by the following formula (1), and has a percentage of the total of integrated intensities of all signals detected at four ranges, δ = 2.14 to 2.17 ppm, δ = 3.46 to 3.49 ppm, δ = 3.62 to 3.69 ppm and δ = 5.42 to 5.46 ppm to the integrated intensity of a signal derived from a methyl group detected at a range of δ = 1.50 to 2.00 ppm of 0.01 to 2.0 % in its 1H-NMR spectrum in heavy chloroform and a viscosity average molecular weight of 10,000 to 100,000.

  一种聚碳酸酯，在熔融成型温度范围内对热分解稳定，无需添加耐热稳定剂，适合熔融成型薄型产品，及其生产方法和成型产品。这种聚碳酸酯主要由下式（1）所代表的递归单元组成、 并在δ＝2.14 至 2.17 ppm、δ＝3.46 至 3.49 ppm、δ＝3.62 至 3.69 ppm 和δ＝5.42 至 5.46 ppm 四个范围内检测到的所有信号的综合强度总和的百分比。在重氯仿中的 1H-NMR 光谱中，在 δ = 1.50 至 2.00 ppm 范围内检测到的来自甲基的信号的综合强度为 0.01 至 2.0%，粘度平均分子量为 10,000 至 100,000。
• 28. Promoters for the dropwise condensation of steam. Part II. Preparation of compounds containing polyfunctional sulphur groups
  作者：L. C. F. Blackman、M. J. S. Dewar

  DOI：10.1039/jr9570000165

  日期：——