| 192801-69-7

• 分子结构分类: 有机化合物 - 有机硫化合物
• CAS: 192801-69-7
• 化学式: C₅H₁₁ClMg
• 分子量: 131.892
• InChiKey: ZPEDJLDBSQDLEI-QCNSCHFVSA-M

反应信息

• 作为反应物：
  描述：

  、 氯化锆(IV) 以 乙醚 、 正己烷 为溶剂， 以69%的产率得到Zr(neopentyl-d)4
  参考文献：
  名称：

  Titanium and zirconium neopentyl chloro complexes, MNpxCl4−x (x = 1−4)

  摘要：

  The comproportionation reaction between the titanium and zirconium homoleptic neopentyl complexes, TiNp4 and ZrNp4 (Np = 2,2'dimethylpropyl; CH2CMe3) and the metal tetrachlorides, TiCl4 and ZrCl4 provides a facile route to all of the titanium and zirconium neopentyl chloro complexes, MNpxCl4-x (x = 1,2,3). All the complexes described are moisture-sensitive, and in the case of the titanium complexes, light-sensitive also. The stability of the complexes at room temperature has also been estimated. The neopentyl chloro complexes, and the isotopically labelled species (where (Np-d) = CH(D)CMe3), have been spectroscopically characterised, the H-1 NMR resonance of the CH2 protons displays an increasing shift to high frequency in the series MNp4, MNp3Cl, MNp2Cl2, MNpCl3. A modified synthesis of Me3CCHDCl from Me3CCHDOH is reported. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00038-7