[Ni(N,N'-bis(2,4-dihydroxybenzylidene)-4,5-dichloro-1,2-phenylenediaminato)] | 807613-85-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: [Ni(N,N'-bis(2,4-dihydroxybenzylidene)-4,5-dichloro-1,2-phenylenediaminato)]
• CAS: 807613-85-0
• 化学式: C₂₀H₁₂Cl₂N₂NiO₄
• 分子量: 473.922
• InChiKey: TTXVVVRUAKLUCX-PGZSYAEMSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ni(N,N'-bis(2,4-dihydroxybenzylidene)-4,5-dichloro-1,2-phenylenediaminato)] 、 sodium t-butanolate 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 以90%的产率得到Ni(II)[N,N'-bis(2,4-dihydroxybenzylidene)-4,5-dichloro-1,2-phenylenediaminato]disodium salt
  参考文献：
  名称：

  Self-assembled monolayers of bis(salicylaldiminato)nickel(II) Schiff-base complexes: synthesis and structure

  摘要：

  The synthesis of two derivatized Ni-II Schiff-base complexes is reported. Self-assembled monolayers (SAMs) have been obtained by reaction of coupling layers, functionalized glass substrates and the derivatized complex precursors. The self-assembled films have been characterized by contact angle measurements, X-ray photoelectron spectroscopy, and UV-Vis absorption spectroscopy. A structure of these SAMs is proposed on the basis of spectroscopic data and molecular metrical parameters. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.04.011
• 作为产物：
  描述：

  N,N'-bis(2,4-dihydroxybenzylidene)-4,5-dichloro-1,2-phenylenediamine 、 nickel(II) acetate tetrahydrate 以 甲醇 为溶剂， 以83%的产率得到[Ni(N,N'-bis(2,4-dihydroxybenzylidene)-4,5-dichloro-1,2-phenylenediaminato)]
  参考文献：
  名称：

  Self-assembled monolayers of bis(salicylaldiminato)nickel(II) Schiff-base complexes: synthesis and structure

  摘要：

  The synthesis of two derivatized Ni-II Schiff-base complexes is reported. Self-assembled monolayers (SAMs) have been obtained by reaction of coupling layers, functionalized glass substrates and the derivatized complex precursors. The self-assembled films have been characterized by contact angle measurements, X-ray photoelectron spectroscopy, and UV-Vis absorption spectroscopy. A structure of these SAMs is proposed on the basis of spectroscopic data and molecular metrical parameters. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.04.011