[(1,3,3-trimethyl bicyclo[2.2.1]heptan-2-olato)bis(indenyl)chlorozirconium(IV)] | 462125-81-1

• 英文名称: [(1,3,3-trimethyl bicyclo[2.2.1]heptan-2-olato)bis(indenyl)chlorozirconium(IV)]
• CAS: 462125-81-1
• 化学式: C₂₈H₃₁ClOZr
• 分子量: 510.231
• InChiKey: XGDHALDITMJLLM-QMKRZPAWSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双茚基锆(VI)二氯化合物 、 lithium 1,3,3-trimethyl bicyclo[2.2.1]heptan-2-olate 以 四氢呋喃 、 苯 为溶剂， 以55.4%的产率得到[(1,3,3-trimethyl bicyclo[2.2.1]heptan-2-olato)bis(indenyl)chlorozirconium(IV)]
  参考文献：
  名称：

  Propylene–ethylene copolymers by one-monomer metallocene catalyzed polymerization

  摘要：

  Propylene polymerization with Ind(2)Zr(OFl)Cl, where Ind = indenyl and OFl = deprotonized moiety of fenchyl alcohol (1,3,3-trimethyl bicyclo[2.2.1]heptan-2-ol) was investigated. The catalyst is capable to polymerize the monomer producing elastomeric propylene-ethylene copolymers containing blocks of ethylene units and atactic propylene sequences. The amount of ethylene units is controlled by the reaction conditions and up to 35.4 mol% ethylene could be obtained. The copolymers with high ethylene sequences content crystallizes resulting in melting transitions in the range of 120degreesC. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(02)00122-x