[Cu(2,2'-bipyrimidine)(N3)2]n | 217790-45-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: [Cu(2,2'-bipyrimidine)(N3)2]n
• CAS: 217790-45-9
• 化学式: C₈H₆CuN₁₀
• 分子量: 305.749
• InChiKey: WDHTZKWHRZIBHG-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (μ-2,2'-bipyrimidine)(NO3)4Cu(II)2}n 、 sodium azide 以 乙醇 、 水 为溶剂， 以90%的产率得到[Cu(2,2'-bipyrimidine)(N3)2]n
  参考文献：
  名称：

  Synthesis, crystal structure and magnetic properties of the first single azido-bridged copper(II) chain [Cu(bpym) (N32]n (bpym + 2,2′-bipyrimidine)

  摘要：

  Single crystals of the copper(II) chain of formula [Cu(bpym) (N-3)(2)](n) (bpym = 2,2'-bipyrimidine) were prepared and characterized by X-ray diffraction methods. The structure consists of neutral chains of copper( II) ions bridged by a single azide group exhibiting the asymmetric end-to-end coordination mode. A terminally bound azide ligand and a didentate bpym group complete the square pyramidal geometry of the metal atom. The intrachain copper-copper separation is 5.063(1) A. The magnetic behaviour was investigated in the temperature range 2.0-290 K. The susceptibility curve exhibits a maximum at 4.9 ii showing the occurrence of a weak intrachain antiferromagnetic coupling. Analysis of the magnetic data using the Heisenberg uniform linear chain model ((H) over cap= -J Sigma (S) over cap(i) .(S) over cap(i+1) ) leads to J= -3.8 cm(-1) and g= 2.12. The value of magnetic coupling of this compound is compared with that observed in the parent double end-to-end azido-bridged dinuclear copper(ll) complexes. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00238-2