| 215854-52-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 215854-52-7
• 化学式: C₃₆H₃₁N₄O₆P₃
• 分子量: 708.587
• InChiKey: HPFDCZRUNCEVHT-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 mercury(II) iodide 以 乙醇 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Synthese und Kristallstrukturen von Quecksilber(II)-iodid-Komplexen mit 3- und 4-pyridylmethylamino- sowie 4-pyridylmethoxy-substituierten Cyclophosphazen-Liganden

  摘要：

  Multifunctional cyclophosphazene ligands with 2-, 3-, and 4-pyridylalkylamino- or 4-pyridylmethoxy groups, N3P3(OC6H5)(5)(NHCH2(C5H4N-2)) (1), N3P3(OC6H5)5 .(NHCH2(C5H4N-3)) (2), N3P3(OC6H5)(5)(NHCH2(C5H4N-4)) (3) and N3P3(OC6H5)(5)(OCH2(C5H4N-4)) (4) are accessible through reactions of monochlorpentaphenoxycyclotriphosphaza-1,3,5-trien with aminomethylpyridine or pyridyl methanolate. 1 does not react with mercury(II) iodide whereas 2-4 yield the metal complexes 2 a, 3 a, and 4 a by interactions of the pyridyl nitrogen atoms. The X-ray single crystal structure analyses of these compounds shows that 2a and 4a are dimers, whereas 3a is a HgI2 polymer with syndiotacticaly al-ranged ligands.

  DOI：

  10.1002/(sici)1521-3749(199810)624:10<1679::aid-zaac1679>3.0.co;2-n