Mn(IV)(1,8-bis(2-hydroxybenzamido)-3,6-diazaoctane(4-)) | 746574-43-6

• 分子结构分类: 有机化合物
• 英文名称: Mn(IV)(1,8-bis(2-hydroxybenzamido)-3,6-diazaoctane(4-))
• CAS: 746574-43-6
• 化学式: C₂₀H₂₂MnN₄O₄
• 分子量: 437.357
• InChiKey: PJGMDSVQYDMGAX-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Mn(IV)(1,8-bis(2-hydroxybenzamido)-3,6-diazaoctane(4-)) 在 glyoxylic acid 作用下， 以 水 为溶剂， 生成 hexaaqua manganese(II) complex
  参考文献：
  名称：

  Oxidation of glyoxylic acid by a mononuclear manganese(IV) complex of 1,8-bis(2-hydroxybenzamido)-3,6-diazaoctane: A kinetics and mechanistic study

  摘要：

  The oxidation of glyoxylic acid (HGI) by (MnL)-L-IV {L4- = tetra deprotonated 1,8-bis(2-hydroxybenzamido)-3,6-diazaoctane) was investigated in the pH range 1.67-10.18, at 25-45 degrees C and 0.5 M ionic strength. The reaction exhibited biphasic kinetics with (MnL-)-L-III as the reactive intermediate. Mn-IV was reduced to Mn-II. The products of oxidation of HGI were identified as formic acid and CO2 in acidic medium, and oxalate in basic medium, consistent with the stoichiometry: -Delta[Mn-IV]/-Delta[HGI] = 1. In acidic medium, both (MnL)-L-IV and (MnL-)-L-III formed outer-sphere adducts with the neutral HGI {HC(OH)(2)COOH} molecule, with an association constant Q(IV) of 28 and 70 M-1, respectively. A similar adduct formation was not observed for the glyoxylate mono anion (Gl(-), CH(OH)(2)(CO2-)) and glyoxylate dianion {Gl(2-), CH(OH)(O-)CO2-}. The rate and activation parameters for the various paths are reported and an outersphere electron transfer mechanism is suggested. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.03.032